A new route to trienals using 2-substituted 2H-pyran-based Wittig reagents

Karl Hemming, Richard J.K. Taylor

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A procedure is presented which allows the six-carbon homologation of aldehydes to give the corresponding trienals via the likely intermediacy of the novel 2-triphenylphosphranylidenemethyl-2H-pyran; application of this methodology to a short synthesis of the marine alarm pheromone, navenone B, is also described.

Original languageEnglish
Pages (from-to)1409-1410
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number18
DOIs
Publication statusPublished - 1 Dec 1993
Externally publishedYes

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