A new synthetic route to donor-acceptor porphyrins

M. John Plater; Stuart Aiken; Grant Bourhill

doi:10.1016/S0040-4020(02)00109-6

A new synthetic route to donor-acceptor porphyrins

M. John Plater, Stuart Aiken, Grant Bourhill

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

Some new donor-acceptor porphyrins have been prepared based on a metallated bis(ethynyl) porphyrin core. 4-(Dimethylamino)phenyl was used as the donor group and 4-nitrophenyl, 4-cyanophenyl and 5-nitrothiazoyl as the acceptor groups. Dipyrrylmethane was used for large scale porphyrin ring synthesis because the absence of methylene substituents reduces the difficulty of substituent scrambling that occurs during porphyrin synthesis.

Original language	English
Pages (from-to)	2405-2413
Number of pages	9
Journal	Tetrahedron
Volume	58
Issue number	12
Early online date	8 Feb 2002
DOIs	https://doi.org/10.1016/S0040-4020(02)00109-6
Publication status	Published - 18 Mar 2002
Externally published	Yes

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AU - Aiken, Stuart

AU - Bourhill, Grant

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AB - Some new donor-acceptor porphyrins have been prepared based on a metallated bis(ethynyl) porphyrin core. 4-(Dimethylamino)phenyl was used as the donor group and 4-nitrophenyl, 4-cyanophenyl and 5-nitrothiazoyl as the acceptor groups. Dipyrrylmethane was used for large scale porphyrin ring synthesis because the absence of methylene substituents reduces the difficulty of substituent scrambling that occurs during porphyrin synthesis.

KW - Palladium and compounds

KW - Porphyrins and analogues

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U2 - 10.1016/S0040-4020(02)00109-6

DO - 10.1016/S0040-4020(02)00109-6

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JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 12

ER -

A new synthetic route to donor-acceptor porphyrins

Abstract

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