Abstract
This paper reports a novel approach of preparing aqueous suspensions of microcrystalline cellulose (MCC) for fabrication of cementitious composites. MCC was dispersed homogeneously in water using Pluronic F-127 as a surfactant with the help of ultrasonication process and the aqueous suspensions were added to cement/sand mixture to prepare cementitious composites. A commonly used stabilizing agent for MCC, carboxy methyl cellulose (CMC) was also used for the comparison purpose. The prepared suspensions were characterized through visual inspection, UV-Vis spectroscopy and optical microscopy. The developed composites were characterized for their bulk density, flexural and compressive properties as well as microstructure. The influence of Pluronic and CMC concentration, superplasticizer, dispersion technique and dispersion temperature on mortar's mechanical performance was thoroughly studied to find out the optimum conditions. Overall, Pluronic (with Pluronic: MCC ratio of 1:5) led to better MCC dispersion as well as dispersion stability as compared to CMC. The best mechanical performance was achieved with Pluronic in combination with superplasticizer using ultrasonication process, resulting in improvement of 106%, 31% and 66% in flexural modulus, flexural strength and compressive strengths, respectively (highest values reported till date). The bulk density and hydration of cementitious composites also improved significantly with the addition of MCC.
| Original language | English |
|---|---|
| Pages (from-to) | 146-161 |
| Number of pages | 16 |
| Journal | Cement and Concrete Composites |
| Volume | 78 |
| Early online date | 25 Jan 2017 |
| DOIs | |
| Publication status | Published - 1 Apr 2017 |
| Externally published | Yes |
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A novel approach of developing micro crystalline cellulose reinforced cementitious composites with enhanced microstructure and mechanical performance. / Parveen, Shama; Rana, Sohel; Fangueiro, Raul; Paiva, Maria Conceição.
In: Cement and Concrete Composites, Vol. 78, 01.04.2017, p. 146-161.Research output: Contribution to journal › Article
TY - JOUR
T1 - A novel approach of developing micro crystalline cellulose reinforced cementitious composites with enhanced microstructure and mechanical performance
AU - Parveen, Shama
AU - Rana, Sohel
AU - Fangueiro, Raul
AU - Paiva, Maria Conceição
PY - 2017/4/1
Y1 - 2017/4/1
N2 - This paper reports a novel approach of preparing aqueous suspensions of microcrystalline cellulose (MCC) for fabrication of cementitious composites. MCC was dispersed homogeneously in water using Pluronic F-127 as a surfactant with the help of ultrasonication process and the aqueous suspensions were added to cement/sand mixture to prepare cementitious composites. A commonly used stabilizing agent for MCC, carboxy methyl cellulose (CMC) was also used for the comparison purpose. The prepared suspensions were characterized through visual inspection, UV-Vis spectroscopy and optical microscopy. The developed composites were characterized for their bulk density, flexural and compressive properties as well as microstructure. The influence of Pluronic and CMC concentration, superplasticizer, dispersion technique and dispersion temperature on mortar's mechanical performance was thoroughly studied to find out the optimum conditions. Overall, Pluronic (with Pluronic: MCC ratio of 1:5) led to better MCC dispersion as well as dispersion stability as compared to CMC. The best mechanical performance was achieved with Pluronic in combination with superplasticizer using ultrasonication process, resulting in improvement of 106%, 31% and 66% in flexural modulus, flexural strength and compressive strengths, respectively (highest values reported till date). The bulk density and hydration of cementitious composites also improved significantly with the addition of MCC.
AB - This paper reports a novel approach of preparing aqueous suspensions of microcrystalline cellulose (MCC) for fabrication of cementitious composites. MCC was dispersed homogeneously in water using Pluronic F-127 as a surfactant with the help of ultrasonication process and the aqueous suspensions were added to cement/sand mixture to prepare cementitious composites. A commonly used stabilizing agent for MCC, carboxy methyl cellulose (CMC) was also used for the comparison purpose. The prepared suspensions were characterized through visual inspection, UV-Vis spectroscopy and optical microscopy. The developed composites were characterized for their bulk density, flexural and compressive properties as well as microstructure. The influence of Pluronic and CMC concentration, superplasticizer, dispersion technique and dispersion temperature on mortar's mechanical performance was thoroughly studied to find out the optimum conditions. Overall, Pluronic (with Pluronic: MCC ratio of 1:5) led to better MCC dispersion as well as dispersion stability as compared to CMC. The best mechanical performance was achieved with Pluronic in combination with superplasticizer using ultrasonication process, resulting in improvement of 106%, 31% and 66% in flexural modulus, flexural strength and compressive strengths, respectively (highest values reported till date). The bulk density and hydration of cementitious composites also improved significantly with the addition of MCC.
KW - Cementitious matrix
KW - Dispersion
KW - Mechanical performance
KW - Microcrystalline cellulose (MCC)
KW - Microstructure
KW - Pluronic F-127
UR - http://www.scopus.com/inward/record.url?scp=85011308910&partnerID=8YFLogxK
U2 - 10.1016/j.cemconcomp.2017.01.004
DO - 10.1016/j.cemconcomp.2017.01.004
M3 - Article
AN - SCOPUS:85011308910
VL - 78
SP - 146
EP - 161
JO - Cement and Concrete Composites
JF - Cement and Concrete Composites
SN - 0958-9465
ER -