A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: A structural, spectroscopic and theoretical analysis

Lindsay P. Harding; Asuka A.T. McRobbie; T. Riis-Johannessen; Simon J.A. Pope; Craig R. Rice; Donna Rollinson; Martina Whitehead

doi:10.1177/1747519820917888

A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: A structural, spectroscopic and theoretical analysis

Lindsay P. Harding, Asuka A.T. McRobbie, T. Riis-Johannessen, Simon J.A. Pope, Craig R. Rice, Donna Rollinson, Martina Whitehead

Research output: Contribution to journal › Article › peer-review

Abstract

A Re(I) complex of 3,3′-diamino-2,2′-bipyridine reacts irreversibly with aldehydes and unhindered ketones in water to form bis-aminal cyclised derivatives with the solid-state structure of the reaction with benzaldehyde reported. This reaction produces a Re(I) complex which is significantly more emissive than the starting compound.

Original language	English
Pages (from-to)	733-737
Number of pages	5
Journal	Journal of Chemical Research
Volume	44
Issue number	11-12
Early online date	19 May 2020
DOIs	https://doi.org/10.1177/1747519820917888
Publication status	Published - 1 Nov 2020

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title = "A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: A structural, spectroscopic and theoretical analysis",

abstract = "A Re(I) complex of 3,3′-diamino-2,2′-bipyridine reacts irreversibly with aldehydes and unhindered ketones in water to form bis-aminal cyclised derivatives with the solid-state structure of the reaction with benzaldehyde reported. This reaction produces a Re(I) complex which is significantly more emissive than the starting compound.",

keywords = "aldehydes, complex, ketones, rhenium, spectroscopic, volatile organic compounds",

author = "Harding, {Lindsay P.} and McRobbie, {Asuka A.T.} and T. Riis-Johannessen and Pope, {Simon J.A.} and Rice, {Craig R.} and Donna Rollinson and Martina Whitehead",

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doi = "10.1177/1747519820917888",

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T1 - A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media

T2 - A structural, spectroscopic and theoretical analysis

AU - Harding, Lindsay P.

AU - McRobbie, Asuka A.T.

AU - Riis-Johannessen, T.

AU - Pope, Simon J.A.

AU - Rice, Craig R.

AU - Rollinson, Donna

AU - Whitehead, Martina

PY - 2020/11/1

Y1 - 2020/11/1

N2 - A Re(I) complex of 3,3′-diamino-2,2′-bipyridine reacts irreversibly with aldehydes and unhindered ketones in water to form bis-aminal cyclised derivatives with the solid-state structure of the reaction with benzaldehyde reported. This reaction produces a Re(I) complex which is significantly more emissive than the starting compound.

AB - A Re(I) complex of 3,3′-diamino-2,2′-bipyridine reacts irreversibly with aldehydes and unhindered ketones in water to form bis-aminal cyclised derivatives with the solid-state structure of the reaction with benzaldehyde reported. This reaction produces a Re(I) complex which is significantly more emissive than the starting compound.

KW - aldehydes

KW - complex

KW - ketones

KW - rhenium

KW - spectroscopic

KW - volatile organic compounds

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DO - 10.1177/1747519820917888

M3 - Article

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JO - Journal of Chemical Research - Part S

JF - Journal of Chemical Research - Part S

SN - 0308-2342

IS - 11-12

ER -

A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: A structural, spectroscopic and theoretical analysis

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