Ag(I) organometallic coordination polymers and capsule with Tris-allyl cyclotriveratrylene derivatives

M.A. Little, M.A. Halcrow, L.P. Harding, M.J. Hardie

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Tris-allyl-cyclotriguaiacylene combines with silver salts to give a range of crystalline network structures and one discrete complex. A number of different coordination modes are found within the complexes including η2-allyl, aryl, and OR groups binding to Ag(I). AgSbF6 gives two types of three-dimensional (3-D) coordination polymer with unusual topologies, along with a discrete Ag2L2 capsule dependent on reaction stoichiometry and reaction conditions. Isostructural coordination chain structures are found with AgBF4 and AgClO4, while use of Ag(CF3SO3) gives two-dimensional (2-D) and 3-D coordination polymers through bridging triflate anions.
LanguageEnglish
Pages9486-9496
Number of pages11
JournalInorganic Chemistry
Volume49
Issue number20
DOIs
Publication statusPublished - 23 Sep 2010

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Organometallics
capsules
coordination polymers
Capsules
Polymers
Derivatives
Silver
Stoichiometry
Anions
stoichiometry
topology
Salts
silver
Topology
Crystalline materials
anions
salts
cyclotriveratrylene

Cite this

Little, M.A. ; Halcrow, M.A. ; Harding, L.P. ; Hardie, M.J. / Ag(I) organometallic coordination polymers and capsule with Tris-allyl cyclotriveratrylene derivatives. In: Inorganic Chemistry. 2010 ; Vol. 49, No. 20. pp. 9486-9496.
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Ag(I) organometallic coordination polymers and capsule with Tris-allyl cyclotriveratrylene derivatives. / Little, M.A.; Halcrow, M.A.; Harding, L.P.; Hardie, M.J.

In: Inorganic Chemistry, Vol. 49, No. 20, 23.09.2010, p. 9486-9496.

Research output: Contribution to journalArticle

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AU - Halcrow, M.A.

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AU - Hardie, M.J.

N1 - cited By 25

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AB - Tris-allyl-cyclotriguaiacylene combines with silver salts to give a range of crystalline network structures and one discrete complex. A number of different coordination modes are found within the complexes including η2-allyl, aryl, and OR groups binding to Ag(I). AgSbF6 gives two types of three-dimensional (3-D) coordination polymer with unusual topologies, along with a discrete Ag2L2 capsule dependent on reaction stoichiometry and reaction conditions. Isostructural coordination chain structures are found with AgBF4 and AgClO4, while use of Ag(CF3SO3) gives two-dimensional (2-D) and 3-D coordination polymers through bridging triflate anions.

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