Cobalt(II)-catalysed decomposition of hydroperoxides. Implications for alkane functionalization

Roy P. Houghton, Craig R. Rice

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

It is proposed that the decomposition of hydroperoxides by cobalt(II) carboxylates and cobalt(II) acetylacetonate involves μ-oxo species which oxidize the hydroperoxide by the bridging oxygen abstracting a hydrogen atom.

Original languageEnglish
Pages (from-to)1893-1897
Number of pages5
JournalPolyhedron
Volume15
Issue number11
DOIs
Publication statusPublished - Jun 1996
Externally publishedYes

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Alkanes
Cobalt
Paraffins
Hydrogen Peroxide
alkanes
cobalt
Decomposition
decomposition
carboxylates
Hydrogen
hydrogen atoms
Oxygen
Atoms
oxygen
acetyl acetonate

Cite this

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title = "Cobalt(II)-catalysed decomposition of hydroperoxides. Implications for alkane functionalization",
abstract = "It is proposed that the decomposition of hydroperoxides by cobalt(II) carboxylates and cobalt(II) acetylacetonate involves μ-oxo species which oxidize the hydroperoxide by the bridging oxygen abstracting a hydrogen atom.",
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Cobalt(II)-catalysed decomposition of hydroperoxides. Implications for alkane functionalization. / Houghton, Roy P.; Rice, Craig R.

In: Polyhedron, Vol. 15, No. 11, 06.1996, p. 1893-1897.

Research output: Contribution to journalArticle

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AU - Rice, Craig R.

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