Cobalt(II)-catalysed decomposition of hydroperoxides. Implications for alkane functionalization

Roy P. Houghton; Craig R. Rice

doi:10.1016/0277-5387(95)00565-X

Cobalt(II)-catalysed decomposition of hydroperoxides. Implications for alkane functionalization

Roy P. Houghton, Craig R. Rice

Cardiff University

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

It is proposed that the decomposition of hydroperoxides by cobalt(II) carboxylates and cobalt(II) acetylacetonate involves μ-oxo species which oxidize the hydroperoxide by the bridging oxygen abstracting a hydrogen atom.

Original language	English
Pages (from-to)	1893-1897
Number of pages	5
Journal	Polyhedron
Volume	15
Issue number	11
DOIs	https://doi.org/10.1016/0277-5387(95)00565-X
Publication status	Published - Jun 1996
Externally published	Yes

Access to Document

10.1016/0277-5387(95)00565-X

Cite this

@article{4a1c5398545b40be87e9b8b7e8f1269f,

title = "Cobalt(II)-catalysed decomposition of hydroperoxides. Implications for alkane functionalization",

abstract = "It is proposed that the decomposition of hydroperoxides by cobalt(II) carboxylates and cobalt(II) acetylacetonate involves μ-oxo species which oxidize the hydroperoxide by the bridging oxygen abstracting a hydrogen atom.",

author = "Houghton, \{Roy P.\} and Rice, \{Craig R.\}",

year = "1996",

month = jun,

doi = "10.1016/0277-5387(95)00565-X",

language = "English",

volume = "15",

pages = "1893--1897",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "11",

}

TY - JOUR

T1 - Cobalt(II)-catalysed decomposition of hydroperoxides. Implications for alkane functionalization

AU - Houghton, Roy P.

AU - Rice, Craig R.

PY - 1996/6

Y1 - 1996/6

N2 - It is proposed that the decomposition of hydroperoxides by cobalt(II) carboxylates and cobalt(II) acetylacetonate involves μ-oxo species which oxidize the hydroperoxide by the bridging oxygen abstracting a hydrogen atom.

AB - It is proposed that the decomposition of hydroperoxides by cobalt(II) carboxylates and cobalt(II) acetylacetonate involves μ-oxo species which oxidize the hydroperoxide by the bridging oxygen abstracting a hydrogen atom.

UR - https://www.scopus.com/pages/publications/0006789429

U2 - 10.1016/0277-5387(95)00565-X

DO - 10.1016/0277-5387(95)00565-X

M3 - Article

AN - SCOPUS:0006789429

SN - 0277-5387

VL - 15

SP - 1893

EP - 1897

JO - Polyhedron

JF - Polyhedron

IS - 11

ER -

Cobalt(II)-catalysed decomposition of hydroperoxides. Implications for alkane functionalization

Abstract

Access to Document

Other files and links

Fingerprint

Cite this