Complexes of Ag(i), Hg(i) and Hg(ii) with multidentate pyrazolyl-pyridine ligands: From mononuclear complexes to coordination polymers via helicates, a mesocate, a cage and a catenate

S.P. Argent, H. Adams, T. Riis-Johannessen, J.C. Jeffery, L.P. Harding, W. Clegg, R.W. Harrington, M.D. Ward

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Abstract

The coordination chemistry of a series of di- and tri-nucleating ligands with Ag(I), Hg(I) and Hg(II) has been investigated. Most of the ligands contain two or three N,N′-bidentate chelating pyrazolyl-pyridine units pendant from a central aromatic spacer; one contains three binding sites (2 + 3 + 2-dentate) in a linear sequence. A series of thirteen complexes has been structurally characterised displaying a wide range of structural types. Bis-bidentate bridging ligands react with Ag(I) to give complexes in which Ag(I) is four-coordinate from two bidentate donors, but the complexes can take the form of one-dimensional coordination polymers, or dinuclear complexes (mesocate or helicate). A tris-bidentate triangular ligand forms a complicated two-dimensional coordination network with Ag(I) in which Ag⋯Ag contacts, as well as metal–ligand coordination bonds, play a significant role. Three dinuclear Hg(I) complexes were isolated which contain an {Hg2}2+ metal–metal bonded core bound to a single bis-bidentate ligand which can span both metal ions. Also characterised were a series of Hg(II) complexes comprising a simple mononuclear four-coordinate Hg(II) complex, a tetrahedral HgII4 cage which incorporates a counter-ion in its central cavity, a trinuclear double helicate, and a trinuclear catenated structure in which two long ligands have spontaneously formed interlocked metallomacrocyclic rings thanks to cyclometallation of two of the Hg(II) centres.
LanguageEnglish
Pages4996-5013
Number of pages18
JournalDalton Transactions
Issue number42
DOIs
Publication statusPublished - 7 Sep 2006

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Polymers
Ligands
Metals
Radiation counters
Chelation
pyridine
Metal ions
Binding Sites

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Argent, S.P. ; Adams, H. ; Riis-Johannessen, T. ; Jeffery, J.C. ; Harding, L.P. ; Clegg, W. ; Harrington, R.W. ; Ward, M.D. / Complexes of Ag(i), Hg(i) and Hg(ii) with multidentate pyrazolyl-pyridine ligands : From mononuclear complexes to coordination polymers via helicates, a mesocate, a cage and a catenate. In: Dalton Transactions. 2006 ; No. 42. pp. 4996-5013.
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Complexes of Ag(i), Hg(i) and Hg(ii) with multidentate pyrazolyl-pyridine ligands : From mononuclear complexes to coordination polymers via helicates, a mesocate, a cage and a catenate. / Argent, S.P.; Adams, H.; Riis-Johannessen, T.; Jeffery, J.C.; Harding, L.P.; Clegg, W.; Harrington, R.W.; Ward, M.D.

In: Dalton Transactions, No. 42, 07.09.2006, p. 4996-5013.

Research output: Contribution to journalArticle

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T2 - Dalton Transactions

AU - Argent, S.P.

AU - Adams, H.

AU - Riis-Johannessen, T.

AU - Jeffery, J.C.

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AU - Harrington, R.W.

AU - Ward, M.D.

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N2 - The coordination chemistry of a series of di- and tri-nucleating ligands with Ag(I), Hg(I) and Hg(II) has been investigated. Most of the ligands contain two or three N,N′-bidentate chelating pyrazolyl-pyridine units pendant from a central aromatic spacer; one contains three binding sites (2 + 3 + 2-dentate) in a linear sequence. A series of thirteen complexes has been structurally characterised displaying a wide range of structural types. Bis-bidentate bridging ligands react with Ag(I) to give complexes in which Ag(I) is four-coordinate from two bidentate donors, but the complexes can take the form of one-dimensional coordination polymers, or dinuclear complexes (mesocate or helicate). A tris-bidentate triangular ligand forms a complicated two-dimensional coordination network with Ag(I) in which Ag⋯Ag contacts, as well as metal–ligand coordination bonds, play a significant role. Three dinuclear Hg(I) complexes were isolated which contain an {Hg2}2+ metal–metal bonded core bound to a single bis-bidentate ligand which can span both metal ions. Also characterised were a series of Hg(II) complexes comprising a simple mononuclear four-coordinate Hg(II) complex, a tetrahedral HgII4 cage which incorporates a counter-ion in its central cavity, a trinuclear double helicate, and a trinuclear catenated structure in which two long ligands have spontaneously formed interlocked metallomacrocyclic rings thanks to cyclometallation of two of the Hg(II) centres.

AB - The coordination chemistry of a series of di- and tri-nucleating ligands with Ag(I), Hg(I) and Hg(II) has been investigated. Most of the ligands contain two or three N,N′-bidentate chelating pyrazolyl-pyridine units pendant from a central aromatic spacer; one contains three binding sites (2 + 3 + 2-dentate) in a linear sequence. A series of thirteen complexes has been structurally characterised displaying a wide range of structural types. Bis-bidentate bridging ligands react with Ag(I) to give complexes in which Ag(I) is four-coordinate from two bidentate donors, but the complexes can take the form of one-dimensional coordination polymers, or dinuclear complexes (mesocate or helicate). A tris-bidentate triangular ligand forms a complicated two-dimensional coordination network with Ag(I) in which Ag⋯Ag contacts, as well as metal–ligand coordination bonds, play a significant role. Three dinuclear Hg(I) complexes were isolated which contain an {Hg2}2+ metal–metal bonded core bound to a single bis-bidentate ligand which can span both metal ions. Also characterised were a series of Hg(II) complexes comprising a simple mononuclear four-coordinate Hg(II) complex, a tetrahedral HgII4 cage which incorporates a counter-ion in its central cavity, a trinuclear double helicate, and a trinuclear catenated structure in which two long ligands have spontaneously formed interlocked metallomacrocyclic rings thanks to cyclometallation of two of the Hg(II) centres.

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JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

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