Concerning the electronic coupling of MoMo quadruple bonds linked by 4,4′-azodibenzoate and comparison with t2g6-Ru(II) centers by 4,4′-azodiphenylcyanamido ligands

Malcolm H. Chisholm, Jason S. D'Acchioli, Christopher M. Hadad, Nathan J. Patmore

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Abstract

From the reactions between Mo2(O2C tBu)4 and each of terephthalic acid and 4,4′-azodibenzoic acid, the compounds [Mo2(O2C tBu)3]2(μ-O2CC6H 4CO2) (1) and [Mo2(O2C tBu)3]2(μ-O2CC6H 4N2C6H4CO2) (2) have been made and characterized by spectroscopic and electrochemical methods. Their electronic structures have been examined by computations employing density functional theory on model compounds where HCO2 substitutes for tBuCO2. On the basis of these studies, the two Mo 2 units are shown to be only weakly coupled and the mixed-valence ions 1+ and 2+ to be valence-trapped and Class II and I, respectively, on the Robin-Day classification scheme for mixed-valence compounds. These results are compared to t2g6-Ru centers linked by 1,4-dicyanamidobenzene and azo-4,4′-diphenylcyanamido bridges for which the mixed-valence ions [Ru-bridge-Ru]5+ have been previously classified as fully delocalized, Class III [Crutchley et al. Inorg. Chem. 2001, 40, 1189; Inorg. Chem. 2004, 43, 1770], and on the basis of results described herein, it is proposed that the latter complex ion is more likely a mixed-valence organic radical where the bridge is oxidized and not the Ru(2+) centers.

Original languageEnglish
Pages (from-to)11035-11042
Number of pages8
JournalInorganic Chemistry
Volume45
Issue number26
DOIs
Publication statusPublished - 1 Dec 2006
Externally publishedYes

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Ions
Ligands
valence
ligands
electronics
Electronic structure
Density functional theory
ions
acids
Acids
substitutes
density functional theory
electronic structure
terephthalic acid

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title = "Concerning the electronic coupling of MoMo quadruple bonds linked by 4,4′-azodibenzoate and comparison with t2g6-Ru(II) centers by 4,4′-azodiphenylcyanamido ligands",
abstract = "From the reactions between Mo2(O2C tBu)4 and each of terephthalic acid and 4,4′-azodibenzoic acid, the compounds [Mo2(O2C tBu)3]2(μ-O2CC6H 4CO2) (1) and [Mo2(O2C tBu)3]2(μ-O2CC6H 4N2C6H4CO2) (2) have been made and characterized by spectroscopic and electrochemical methods. Their electronic structures have been examined by computations employing density functional theory on model compounds where HCO2 substitutes for tBuCO2. On the basis of these studies, the two Mo 2 units are shown to be only weakly coupled and the mixed-valence ions 1+ and 2+ to be valence-trapped and Class II and I, respectively, on the Robin-Day classification scheme for mixed-valence compounds. These results are compared to t2g6-Ru centers linked by 1,4-dicyanamidobenzene and azo-4,4′-diphenylcyanamido bridges for which the mixed-valence ions [Ru-bridge-Ru]5+ have been previously classified as fully delocalized, Class III [Crutchley et al. Inorg. Chem. 2001, 40, 1189; Inorg. Chem. 2004, 43, 1770], and on the basis of results described herein, it is proposed that the latter complex ion is more likely a mixed-valence organic radical where the bridge is oxidized and not the Ru(2+) centers.",
author = "Chisholm, {Malcolm H.} and D'Acchioli, {Jason S.} and Hadad, {Christopher M.} and Patmore, {Nathan J.}",
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Concerning the electronic coupling of MoMo quadruple bonds linked by 4,4′-azodibenzoate and comparison with t2g6-Ru(II) centers by 4,4′-azodiphenylcyanamido ligands. / Chisholm, Malcolm H.; D'Acchioli, Jason S.; Hadad, Christopher M.; Patmore, Nathan J.

In: Inorganic Chemistry, Vol. 45, No. 26, 01.12.2006, p. 11035-11042.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Concerning the electronic coupling of MoMo quadruple bonds linked by 4,4′-azodibenzoate and comparison with t2g6-Ru(II) centers by 4,4′-azodiphenylcyanamido ligands

AU - Chisholm, Malcolm H.

AU - D'Acchioli, Jason S.

AU - Hadad, Christopher M.

AU - Patmore, Nathan J.

PY - 2006/12/1

Y1 - 2006/12/1

N2 - From the reactions between Mo2(O2C tBu)4 and each of terephthalic acid and 4,4′-azodibenzoic acid, the compounds [Mo2(O2C tBu)3]2(μ-O2CC6H 4CO2) (1) and [Mo2(O2C tBu)3]2(μ-O2CC6H 4N2C6H4CO2) (2) have been made and characterized by spectroscopic and electrochemical methods. Their electronic structures have been examined by computations employing density functional theory on model compounds where HCO2 substitutes for tBuCO2. On the basis of these studies, the two Mo 2 units are shown to be only weakly coupled and the mixed-valence ions 1+ and 2+ to be valence-trapped and Class II and I, respectively, on the Robin-Day classification scheme for mixed-valence compounds. These results are compared to t2g6-Ru centers linked by 1,4-dicyanamidobenzene and azo-4,4′-diphenylcyanamido bridges for which the mixed-valence ions [Ru-bridge-Ru]5+ have been previously classified as fully delocalized, Class III [Crutchley et al. Inorg. Chem. 2001, 40, 1189; Inorg. Chem. 2004, 43, 1770], and on the basis of results described herein, it is proposed that the latter complex ion is more likely a mixed-valence organic radical where the bridge is oxidized and not the Ru(2+) centers.

AB - From the reactions between Mo2(O2C tBu)4 and each of terephthalic acid and 4,4′-azodibenzoic acid, the compounds [Mo2(O2C tBu)3]2(μ-O2CC6H 4CO2) (1) and [Mo2(O2C tBu)3]2(μ-O2CC6H 4N2C6H4CO2) (2) have been made and characterized by spectroscopic and electrochemical methods. Their electronic structures have been examined by computations employing density functional theory on model compounds where HCO2 substitutes for tBuCO2. On the basis of these studies, the two Mo 2 units are shown to be only weakly coupled and the mixed-valence ions 1+ and 2+ to be valence-trapped and Class II and I, respectively, on the Robin-Day classification scheme for mixed-valence compounds. These results are compared to t2g6-Ru centers linked by 1,4-dicyanamidobenzene and azo-4,4′-diphenylcyanamido bridges for which the mixed-valence ions [Ru-bridge-Ru]5+ have been previously classified as fully delocalized, Class III [Crutchley et al. Inorg. Chem. 2001, 40, 1189; Inorg. Chem. 2004, 43, 1770], and on the basis of results described herein, it is proposed that the latter complex ion is more likely a mixed-valence organic radical where the bridge is oxidized and not the Ru(2+) centers.

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SP - 11035

EP - 11042

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 26

ER -