Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

Mikhail V. Barybin, Malcolm H. Chisholm, Nathan J. Patmore, Randall E. Robinson, Namrata Singh

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The preparation and molecular structure of a W2 4+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π-M2δ-ligand π conjugation.

Original languageEnglish
Pages (from-to)3652-3654
Number of pages3
JournalChemical Communications
Issue number35
Early online date7 Aug 2007
DOIs
Publication statusPublished - 6 Sep 2007
Externally publishedYes

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Tungsten
Molecular structure
Electronic structure
Ligands

Cite this

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title = "Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands",
abstract = "The preparation and molecular structure of a W2 4+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π-M2δ-ligand π conjugation.",
author = "Barybin, {Mikhail V.} and Chisholm, {Malcolm H.} and Patmore, {Nathan J.} and Robinson, {Randall E.} and Namrata Singh",
year = "2007",
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doi = "10.1039/b708746b",
language = "English",
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journal = "Chemical Communications",
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publisher = "Royal Society of Chemistry",
number = "35",

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Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands. / Barybin, Mikhail V.; Chisholm, Malcolm H.; Patmore, Nathan J.; Robinson, Randall E.; Singh, Namrata.

In: Chemical Communications, No. 35, 06.09.2007, p. 3652-3654.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

AU - Barybin, Mikhail V.

AU - Chisholm, Malcolm H.

AU - Patmore, Nathan J.

AU - Robinson, Randall E.

AU - Singh, Namrata

PY - 2007/9/6

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AB - The preparation and molecular structure of a W2 4+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π-M2δ-ligand π conjugation.

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