Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

Mikhail V. Barybin; Malcolm H. Chisholm; Nathan J. Patmore; Randall E. Robinson; Namrata Singh

doi:10.1039/b708746b

Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

Mikhail V. Barybin, Malcolm H. Chisholm, Nathan J. Patmore, Randall E. Robinson, Namrata Singh

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The preparation and molecular structure of a W₂ ⁴⁺-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π-M₂δ-ligand π conjugation.

Original language	English
Pages (from-to)	3652-3654
Number of pages	3
Journal	Chemical Communications
Issue number	35
Early online date	7 Aug 2007
DOIs	https://doi.org/10.1039/b708746b
Publication status	Published - 6 Sept 2007
Externally published	Yes

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title = "Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands",

abstract = "The preparation and molecular structure of a W2 4+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π-M2δ-ligand π conjugation.",

author = "Barybin, \{Mikhail V.\} and Chisholm, \{Malcolm H.\} and Patmore, \{Nathan J.\} and Robinson, \{Randall E.\} and Namrata Singh",

year = "2007",

month = sep,

day = "6",

doi = "10.1039/b708746b",

language = "English",

pages = "3652--3654",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

AU - Barybin, Mikhail V.

AU - Chisholm, Malcolm H.

AU - Patmore, Nathan J.

AU - Robinson, Randall E.

AU - Singh, Namrata

PY - 2007/9/6

Y1 - 2007/9/6

N2 - The preparation and molecular structure of a W2 4+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π-M2δ-ligand π conjugation.

AB - The preparation and molecular structure of a W2 4+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π-M2δ-ligand π conjugation.

UR - https://www.scopus.com/pages/publications/34548307067

U2 - 10.1039/b708746b

DO - 10.1039/b708746b

M3 - Article

AN - SCOPUS:34548307067

SN - 1359-7345

SP - 3652

EP - 3654

JO - Chemical Communications

JF - Chemical Communications

IS - 35

ER -

Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands

Abstract

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