Abstract
A convenient, highly regioselective synthesis of five-membered cyclic vinyl(aryl)iodonium salts directly from β-iodostyrenes is presented. An X-ray crystal structure confirms the identity of these heterocycles. These λ3-iodanes can be converted rapidly into functionalized arylacetylenes by treatment with mild base or undergo SNV reactions with nonbasic nucleophiles.
Original language | English |
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Pages (from-to) | 6936-6939 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 21 |
Issue number | 17 |
Early online date | 27 Aug 2019 |
DOIs | |
Publication status | Published - 6 Sep 2019 |
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Dive into the research topics of 'Cyclic Vinyl(aryl)iodonium Salts: Synthesis and Reactivity'. Together they form a unique fingerprint.Profiles
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Wesley Moran
- Department of Chemical Sciences - Reader
- School of Applied Sciences
- Chemical Synthesis and Design Centre - Member
- Structural, Molecular and Dynamic Modelling Centre - Associate Member
Person: Academic