Detection and Reactivity of Pd((C8H14)PCH 2CH2P(C8H14))(CHPhCH 2Ph)(H) as Determined by Parahydrogen-Enhanced NMR Spectroscopy

John P. Dunne; S. Aiken; Simon B. Duckett; Denis Konya; Karina Q. Almeida Leñero; Eite Drent

doi:10.1021/ja044875f

Detection and Reactivity of Pd((C8H14)PCH 2CH2P(C8H14))(CHPhCH 2Ph)(H) as Determined by Parahydrogen-Enhanced NMR Spectroscopy

John P. Dunne, S. Aiken, Simon B. Duckett, Denis Konya, Karina Q. Almeida Leñero, Eite Drent

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Pd(bcope)(OTf)2 (where bcope is (C₈H₁₄)PCH₂CH₂P(C₈H₁₄)) is shown to react with an alkyne in the presence of parahydrogen to form alkyl hydrides, such as Pd(bcope)(CHPhCH₂Ph)(H), that are detectable by NMR spectroscopy because the proton resonances of the alkyl arm appear with strongly enhanced signal strengths.

Original language	English
Pages (from-to)	16708-16709
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	51
DOIs	https://doi.org/10.1021/ja044875f
Publication status	Published - 29 Dec 2004
Externally published	Yes

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title = "Detection and Reactivity of Pd((C8H14)PCH 2CH2P(C8H14))(CHPhCH 2Ph)(H) as Determined by Parahydrogen-Enhanced NMR Spectroscopy",

abstract = "Pd(bcope)(OTf)2 (where bcope is (C8H14)PCH2CH2P(C8H14)) is shown to react with an alkyne in the presence of parahydrogen to form alkyl hydrides, such as Pd(bcope)(CHPhCH2Ph)(H), that are detectable by NMR spectroscopy because the proton resonances of the alkyl arm appear with strongly enhanced signal strengths.",

author = "Dunne, {John P.} and S. Aiken and Duckett, {Simon B.} and Denis Konya and {Almeida Le{\~n}ero}, {Karina Q.} and Eite Drent",

year = "2004",

month = dec,

day = "29",

doi = "10.1021/ja044875f",

language = "English",

volume = "126",

pages = "16708--16709",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Detection and Reactivity of Pd((C8H14)PCH 2CH2P(C8H14))(CHPhCH 2Ph)(H) as Determined by Parahydrogen-Enhanced NMR Spectroscopy

AU - Dunne, John P.

AU - Aiken, S.

AU - Duckett, Simon B.

AU - Konya, Denis

AU - Almeida Leñero, Karina Q.

AU - Drent, Eite

PY - 2004/12/29

Y1 - 2004/12/29

N2 - Pd(bcope)(OTf)2 (where bcope is (C8H14)PCH2CH2P(C8H14)) is shown to react with an alkyne in the presence of parahydrogen to form alkyl hydrides, such as Pd(bcope)(CHPhCH2Ph)(H), that are detectable by NMR spectroscopy because the proton resonances of the alkyl arm appear with strongly enhanced signal strengths.

AB - Pd(bcope)(OTf)2 (where bcope is (C8H14)PCH2CH2P(C8H14)) is shown to react with an alkyne in the presence of parahydrogen to form alkyl hydrides, such as Pd(bcope)(CHPhCH2Ph)(H), that are detectable by NMR spectroscopy because the proton resonances of the alkyl arm appear with strongly enhanced signal strengths.

UR - http://www.scopus.com/inward/record.url?scp=11244354298&partnerID=8YFLogxK

UR - http://pubs.acs.org/journal/jacsat

U2 - 10.1021/ja044875f

DO - 10.1021/ja044875f

M3 - Article

AN - SCOPUS:11244354298

VL - 126

SP - 16708

EP - 16709

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 51

ER -

Detection and Reactivity of Pd((C8H14)PCH 2CH2P(C8H14))(CHPhCH 2Ph)(H) as Determined by Parahydrogen-Enhanced NMR Spectroscopy

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