Detection and Reactivity of Pd((C8H14)PCH 2CH2P(C8H14))(CHPhCH 2Ph)(H) as Determined by Parahydrogen-Enhanced NMR Spectroscopy

John P. Dunne, S. Aiken, Simon B. Duckett, Denis Konya, Karina Q. Almeida Leñero, Eite Drent

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Pd(bcope)(OTf)2 (where bcope is (C8H14)PCH2CH2P(C8H14)) is shown to react with an alkyne in the presence of parahydrogen to form alkyl hydrides, such as Pd(bcope)(CHPhCH2Ph)(H), that are detectable by NMR spectroscopy because the proton resonances of the alkyl arm appear with strongly enhanced signal strengths.

Original languageEnglish
Pages (from-to)16708-16709
Number of pages2
JournalJournal of the American Chemical Society
Volume126
Issue number51
DOIs
Publication statusPublished - 29 Dec 2004
Externally publishedYes

    Fingerprint

Cite this