Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

N. C. Norman, A. G. Orpen, M. J. Quayle, C. R. Rice

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2-, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2-.

LanguageEnglish
Pages837-839
Number of pages3
JournalNew Journal of Chemistry
Volume24
Issue number11
DOIs
Publication statusPublished - 2000
Externally publishedYes

Fingerprint

X ray crystallography
Salts
diborane
dithiol

Cite this

Norman, N. C. ; Orpen, A. G. ; Quayle, M. J. ; Rice, C. R. / Diborane(4) compounds incorporating thio- and seleno-carboranyl groups. In: New Journal of Chemistry. 2000 ; Vol. 24, No. 11. pp. 837-839.
@article{1e53a1b9e2224bd3b3ec11967ca613af,
title = "Diborane(4) compounds incorporating thio- and seleno-carboranyl groups",
abstract = "The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2-, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2-.",
author = "Norman, {N. C.} and Orpen, {A. G.} and Quayle, {M. J.} and Rice, {C. R.}",
year = "2000",
doi = "10.1039/b004942p",
language = "English",
volume = "24",
pages = "837--839",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "Royal Society of Chemistry",
number = "11",

}

Diborane(4) compounds incorporating thio- and seleno-carboranyl groups. / Norman, N. C.; Orpen, A. G.; Quayle, M. J.; Rice, C. R.

In: New Journal of Chemistry, Vol. 24, No. 11, 2000, p. 837-839.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

AU - Norman, N. C.

AU - Orpen, A. G.

AU - Quayle, M. J.

AU - Rice, C. R.

PY - 2000

Y1 - 2000

N2 - The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2-, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2-.

AB - The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2-, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2-.

UR - http://www.scopus.com/inward/record.url?scp=0033668540&partnerID=8YFLogxK

U2 - 10.1039/b004942p

DO - 10.1039/b004942p

M3 - Article

VL - 24

SP - 837

EP - 839

JO - New Journal of Chemistry

T2 - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 11

ER -