Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

N. C. Norman; A. G. Orpen; M. J. Quayle; C. R. Rice

doi:10.1039/b004942p

Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

N. C. Norman, A. G. Orpen, M. J. Quayle, C. R. Rice

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

The reaction between B₂(NMe₂)₄ and the carborane dithiol C₂B₁₀H₁₀(SH)₂, followed by addition of HCl affords the [NH₂Me₂]⁺ salt of the dianion [B₂Cl₂(S₂C₂B₁₀H₁₀)₂]^2-, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C₂B₁₀H₁₀(SeH)₂ (generated in situ) afforded a compound containing the dianion [B₂(Se₂C₂B₁₀H₁₀)₃]^2-.

Original language	English
Pages (from-to)	837-839
Number of pages	3
Journal	New Journal of Chemistry
Volume	24
Issue number	11
DOIs	https://doi.org/10.1039/b004942p
Publication status	Published - 2000
Externally published	Yes

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title = "Diborane(4) compounds incorporating thio- and seleno-carboranyl groups",

abstract = "The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2-, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2-.",

author = "Norman, {N. C.} and Orpen, {A. G.} and Quayle, {M. J.} and Rice, {C. R.}",

year = "2000",

doi = "10.1039/b004942p",

language = "English",

volume = "24",

pages = "837--839",

journal = "New Journal of Chemistry",

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publisher = "Royal Society of Chemistry",

number = "11",

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T1 - Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

AU - Norman, N. C.

AU - Orpen, A. G.

AU - Quayle, M. J.

AU - Rice, C. R.

PY - 2000

Y1 - 2000

N2 - The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2-, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2-.

AB - The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2-, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2-.

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U2 - 10.1039/b004942p

DO - 10.1039/b004942p

M3 - Article

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SP - 837

EP - 839

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 11

ER -

Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

Abstract

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