Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion

Robert Faulkner; Nathan Patmore; Craig Rice; Christopher Slater

doi:10.1039/C8CC04900A

Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion

Robert Faulkner, Nathan Patmore, Craig Rice, Christopher Slater

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The ligands L ¹ and L ² both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu ₂L ₂(H ₂PO ₄)] ³⁺). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu ₃(L ¹) ₃(O ₃POBF ₃)] ³⁺ and [Cu ₂(L ²) ₂(O ₂P(OBF ₃) ₂)] ⁺.

Original language	English
Pages (from-to)	9159 - 9162
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	66
Early online date	19 Jul 2018
DOIs	https://doi.org/10.1039/C8CC04900A
Publication status	Published - 25 Aug 2018

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title = "Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion",

abstract = "The ligands L 1 and L 2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu 2L 2(H 2PO 4)] 3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu 3(L 1) 3(O 3POBF 3)] 3+ and [Cu 2(L 2) 2(O 2P(OBF 3) 2)] +. ",

keywords = "chemical compound, dihydrogen phosphate, phosphate, tetrafluoroborate, unclassified drug",

author = "Robert Faulkner and Nathan Patmore and Craig Rice and Christopher Slater",

year = "2018",

month = aug,

day = "25",

doi = "10.1039/C8CC04900A",

language = "English",

volume = "54",

pages = "9159 -- 9162",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "66",

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T1 - Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion

AU - Faulkner, Robert

AU - Patmore, Nathan

AU - Rice, Craig

AU - Slater, Christopher

PY - 2018/8/25

Y1 - 2018/8/25

N2 - The ligands L 1 and L 2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu 2L 2(H 2PO 4)] 3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu 3(L 1) 3(O 3POBF 3)] 3+ and [Cu 2(L 2) 2(O 2P(OBF 3) 2)] +.

AB - The ligands L 1 and L 2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu 2L 2(H 2PO 4)] 3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu 3(L 1) 3(O 3POBF 3)] 3+ and [Cu 2(L 2) 2(O 2P(OBF 3) 2)] +.

KW - chemical compound

KW - dihydrogen phosphate

KW - phosphate

KW - tetrafluoroborate

KW - unclassified drug

UR - http://www.scopus.com/inward/record.url?scp=85051680339&partnerID=8YFLogxK

U2 - 10.1039/C8CC04900A

DO - 10.1039/C8CC04900A

M3 - Article

VL - 54

SP - 9159

EP - 9162

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 66

ER -

Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion

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Craig Rice

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Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion

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Craig Rice

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