Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion.

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Abstract

The ligands L 1 and L 2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu 2L 2(H 2PO 4)] 3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu 3(L 1) 3(O 3POBF 3)] 3+ and [Cu 2(L 2) 2(O 2P(OBF 3) 2)] +.

Original languageEnglish
Pages (from-to)9159 - 9162
Number of pages4
JournalChemical Communications
Volume54
Issue number66
DOIs
Publication statusPublished - 19 Jul 2018

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Anions
Phosphates
Negative ions
Ligands

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title = "Dihydrogen Phosphate-containing Dinuclear Double Assemblies that Demonstrate Phosphate Reactivity to the Tetrafluoroborate Anion.",
abstract = "The ligands L 1 and L 2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu 2L 2(H 2PO 4)] 3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu 3(L 1) 3(O 3POBF 3)] 3+ and [Cu 2(L 2) 2(O 2P(OBF 3) 2)] +.",
author = "Robert Faulkner and Nathan Patmore and Craig Rice and Christopher Slater",
year = "2018",
month = "7",
day = "19",
doi = "10.1039/C8CC04900A",
language = "English",
volume = "54",
pages = "9159 -- 9162",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
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AU - Faulkner, Robert

AU - Patmore, Nathan

AU - Rice, Craig

AU - Slater, Christopher

PY - 2018/7/19

Y1 - 2018/7/19

N2 - The ligands L 1 and L 2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu 2L 2(H 2PO 4)] 3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu 3(L 1) 3(O 3POBF 3)] 3+ and [Cu 2(L 2) 2(O 2P(OBF 3) 2)] +.

AB - The ligands L 1 and L 2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu 2L 2(H 2PO 4)] 3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu 3(L 1) 3(O 3POBF 3)] 3+ and [Cu 2(L 2) 2(O 2P(OBF 3) 2)] +.

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U2 - 10.1039/C8CC04900A

DO - 10.1039/C8CC04900A

M3 - Article

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SP - 9159

EP - 9162

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

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