Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Jihan  Qurban; Mohamed Elsherbini; Thomas Wirth

doi:10.1021/acs.joc.7b01571

Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Jihan Qurban, Mohamed Elsherbini, Thomas Wirth

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

Original language	English
Pages (from-to)	11872-11876
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	82
Issue number	22
Early online date	31 Jul 2017
DOIs	https://doi.org/10.1021/acs.joc.7b01571
Publication status	Published - 17 Nov 2017
Externally published	Yes

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AB - Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

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JF - Journal of Organic Chemistry

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Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Abstract

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