Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.
|Number of pages||5|
|Journal||Journal of Organic Chemistry|
|Early online date||31 Jul 2017|
|Publication status||Published - 17 Nov 2017|