Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Jihan  Qurban; Mohamed Elsherbini; Thomas Wirth

doi:10.1021/acs.joc.7b01571

Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Jihan Qurban, Mohamed Elsherbini, Thomas Wirth

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

Original language	English
Pages (from-to)	11872-11876
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	82
Issue number	22
Early online date	31 Jul 2017
DOIs	https://doi.org/10.1021/acs.joc.7b01571
Publication status	Published - 17 Nov 2017
Externally published	Yes

Access to Document

10.1021/acs.joc.7b01571Licence: Other

Cite this

@article{2c1f148ac41e4bc8b70172de686536a7,

title = "Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents",

abstract = "Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.",

author = "Jihan Qurban and Mohamed Elsherbini and Thomas Wirth",

year = "2017",

month = nov,

day = "17",

doi = "10.1021/acs.joc.7b01571",

language = "English",

volume = "82",

pages = "11872--11876",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

AU - Qurban, Jihan

AU - Elsherbini, Mohamed

AU - Wirth, Thomas

PY - 2017/11/17

Y1 - 2017/11/17

N2 - Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

AB - Novel electron-deficient chiral hypervalent iodine reagents were prepared in good overall yields. The reactivity and stereoselectivity of these reagents in oxidative rearrangements of alkenes to α-aryl ketones were investigated. The results show that the new reagents have good reactivity and generate products with high enantiomeric excess.

UR - https://www2.scopus.com/record/display.uri?eid=2-s2.0-85034593159&origin=resultslist&sort=plf-f&src=s&st1=Electron-Deficient+Chiral+Lactic+Acid-Based+Hypervalent+Iodine+Reagents&st2=&sid=4d954266dd9c267807b62366fd2a28f2&sot=b&sdt=b&sl=86&s=TITLE-ABS-KEY%28Electron-Deficient+Chiral+Lactic+Acid-Based+Hypervalent+Iodine+Reagents%29&relpos=0&citeCnt=12&searchTerm=

U2 - 10.1021/acs.joc.7b01571

DO - 10.1021/acs.joc.7b01571

M3 - Article

SN - 0022-3263

VL - 82

SP - 11872

EP - 11876

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 22

ER -

Electron-Deficient Chiral Lactic Acid-Based Hypervalent Iodine Reagents

Abstract

Access to Document

Other files and links

Fingerprint

Cite this