Enantioselective Diamination with Novel Chiral Hypervalent Iodine Catalysts

Pushpak Mizar, Aragorn Laverny, Mohamed Elsherbini, Umar Farid, Michael Brown, Florence Malmedy, Thomas Wirth

Research output: Contribution to journalArticle

78 Citations (Scopus)

Abstract

Vicinal diamines constitute one the most important functional motif in organic chemistry because of its wide occurrence in a variety of biological and pharmaceutical molecules. We report an efficient metal‐free, highly stereoselective intramolecular diamination using a novel chiral hypervalent iodine reagent together with its application as an efficient catalyst for the synthesis of diamines.
Original languageEnglish
Pages (from-to)9910-9913
Number of pages4
JournalChemistry - A European Journal
Volume20
Issue number32
Early online date17 Jul 2014
DOIs
Publication statusPublished - 4 Aug 2014
Externally publishedYes

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