TY - JOUR
T1 - Equilibria between Enamine and α,β-Unsaturated Imine in Cephalosporin Hydrolysis
AU - Buckwell, Stephen
AU - Page, Michael I.
AU - Longridge, Jethro L.
PY - 1986/7/1
Y1 - 1986/7/1
N2 - The normal product of hydrolysis of cephalosporins with a leaving group at C-3′ is an α,β-unsaturated imine which is demonstrated to be in equilibrium with its precursor, an enamine; the equilibrium constants for this process are reported for thiolate anions which generate a Bronsted βlg of 0.71.
AB - The normal product of hydrolysis of cephalosporins with a leaving group at C-3′ is an α,β-unsaturated imine which is demonstrated to be in equilibrium with its precursor, an enamine; the equilibrium constants for this process are reported for thiolate anions which generate a Bronsted βlg of 0.71.
UR - http://www.scopus.com/inward/record.url?scp=37049078888&partnerID=8YFLogxK
U2 - 10.1039/C39860001039
DO - 10.1039/C39860001039
M3 - Article
AN - SCOPUS:37049078888
SP - 1039
EP - 1040
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 13
ER -