Evidence for the formation of isothiocyanate during sulfurisation of phosphines and phosphites using xanthane hydride

Jiří Hanusek; Mark A. Russell; Andrew P. Laws; Michael I. Page

doi:10.1016/j.tetlet.2006.11.075

Evidence for the formation of isothiocyanate during sulfurisation of phosphines and phosphites using xanthane hydride

Jiří Hanusek, Mark A. Russell, Andrew P. Laws, Michael I. Page

University of Pardubice

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Contrary to a previous report, the sulfurisation of triphenylphosphines and trialkyl phosphites by 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products but unstable thiocarbamoyl isothiocyanate which has been trapped with nucleophiles.

Original language	English
Pages (from-to)	417-419
Number of pages	3
Journal	Tetrahedron Letters
Volume	48
Issue number	3
Early online date	1 Dec 2006
DOIs	https://doi.org/10.1016/j.tetlet.2006.11.075
Publication status	Published - 15 Jan 2007

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title = "Evidence for the formation of isothiocyanate during sulfurisation of phosphines and phosphites using xanthane hydride",

abstract = "Contrary to a previous report, the sulfurisation of triphenylphosphines and trialkyl phosphites by 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products but unstable thiocarbamoyl isothiocyanate which has been trapped with nucleophiles.",

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AU - Hanusek, Jiří

AU - Russell, Mark A.

AU - Laws, Andrew P.

AU - Page, Michael I.

PY - 2007/1/15

Y1 - 2007/1/15

N2 - Contrary to a previous report, the sulfurisation of triphenylphosphines and trialkyl phosphites by 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products but unstable thiocarbamoyl isothiocyanate which has been trapped with nucleophiles.

AB - Contrary to a previous report, the sulfurisation of triphenylphosphines and trialkyl phosphites by 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products but unstable thiocarbamoyl isothiocyanate which has been trapped with nucleophiles.

UR - https://www.scopus.com/pages/publications/33845425257

U2 - 10.1016/j.tetlet.2006.11.075

DO - 10.1016/j.tetlet.2006.11.075

M3 - Article

AN - SCOPUS:33845425257

SN - 0040-4039

VL - 48

SP - 417

EP - 419

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 3

ER -

Evidence for the formation of isothiocyanate during sulfurisation of phosphines and phosphites using xanthane hydride

Abstract

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