Expedient syntheses of the rotenoid and thiorotenoid systems

Christopher D. Gabbutt; John D. Hepworth; B. Mark Heron

doi:10.1039/P19940000653

Expedient syntheses of the rotenoid and thiorotenoid systems

Christopher D. Gabbutt, John D. Hepworth, B. Mark Heron

University of Lancashire

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A simple four-step synthesis of a 6,6-disubstituted 6a,12a-dihydro-6H,12H- [1]benzopyrano[3,4,-b]-[1]benzopyran-12-one 6 from a chroman-4-one 3 is described. Application of the synthetic strategy to a thiochroman-4-one leads to the 5-thiorotenoid system.

Original language	English
Pages (from-to)	653-657
Number of pages	5
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	6
DOIs	https://doi.org/10.1039/P19940000653
Publication status	Published - 1 Dec 1994
Externally published	Yes

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title = "Expedient syntheses of the rotenoid and thiorotenoid systems",

abstract = "A simple four-step synthesis of a 6,6-disubstituted 6a,12a-dihydro-6H,12H- [1]benzopyrano[3,4,-b]-[1]benzopyran-12-one 6 from a chroman-4-one 3 is described. Application of the synthetic strategy to a thiochroman-4-one leads to the 5-thiorotenoid system.",

author = "Gabbutt, \{Christopher D.\} and Hepworth, \{John D.\} and Heron, \{B. Mark\}",

year = "1994",

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AU - Gabbutt, Christopher D.

AU - Hepworth, John D.

AU - Heron, B. Mark

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Y1 - 1994/12/1

N2 - A simple four-step synthesis of a 6,6-disubstituted 6a,12a-dihydro-6H,12H- [1]benzopyrano[3,4,-b]-[1]benzopyran-12-one 6 from a chroman-4-one 3 is described. Application of the synthetic strategy to a thiochroman-4-one leads to the 5-thiorotenoid system.

AB - A simple four-step synthesis of a 6,6-disubstituted 6a,12a-dihydro-6H,12H- [1]benzopyrano[3,4,-b]-[1]benzopyran-12-one 6 from a chroman-4-one 3 is described. Application of the synthetic strategy to a thiochroman-4-one leads to the 5-thiorotenoid system.

UR - https://www.scopus.com/pages/publications/37049067866

U2 - 10.1039/P19940000653

DO - 10.1039/P19940000653

M3 - Article

AN - SCOPUS:37049067866

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JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 6

ER -

Expedient syntheses of the rotenoid and thiorotenoid systems

Abstract

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