Formation and Reactivity of Ir(III) Hydroxycarbonyl Complexes

Keyphrases

• Activation Parameters 100%
• K(I) 100%
• Ir(III) 100%
• Thermally Stable 50%
• Dimer Formation 50%
• Nucleophilic Attack 50%
• Decarboxylation 50%
• Rate-determining Step 50%
• Electron-rich 50%
• Bond Cleavage 50%
• Dehydroxylation 50%
• Relative Reactivity 50%
• Hydrotris(pyrazolyl)borate 50%
• Thermal Decarboxylation 50%
• Order-k 50%
• Protonation 50%
• X-ray Crystal Structure 50%
• MeCN 50%
• Kinetic Isotope Effect 50%
• First-order Process 50%
• Carbonyl Ligands 50%
• Kinetic Study 50%
• H-bonding Interaction 50%
• Borate 50%

Chemistry

• formation 100%
• Decarboxylation 100%
• Borate 100%
• dimer 50%
• Crystal Structure 50%
• Kinetic Isotope Effect 50%
• Kinetic Study 50%
• protonation 50%
• Dehydroxylation 50%
• Rate-Determining Step 50%