Fracture toughness in some hetero-modulus composite carbides: carbon inclusions and voids

O. Popov, V. Vishnyakov

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Structure and mechanical characteristics of dense ceramic composites synthesised by reactive hot pressing of TiC–B4C powder mixtures at 1800–1950°C under 30 MPa were investigated by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM and EDX). The results show that during hot pressing solid-phase chemical reaction 2TiC + B4C = 2TiB2 + 3C has occurred with final products like TiB2–TiC–C, TiB2–C or TiB2–B4C–C hetero-modulus composite formation with around one micrometer size carbon precipitates. The fracture toughness depends on the amount of graphite precipitation and has a distinct maximum K1C = 10 MPa m1/2 at nearly 7 vol.-% of carbon precipitate. The fracture toughness behaviour is explained by the developed model of crack propagation. Within the model, it is shown that pores (voids) and low-modulus carbon inclusions blunt the cracks and can increase ceramic toughness in some cases.

LanguageEnglish
Pages61-70
Number of pages10
JournalAdvances in Applied Ceramics
Volume116
Issue number2
Early online date21 Jul 2016
DOIs
Publication statusPublished - 2017

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Carbides
Fracture toughness
Carbon
Hot pressing
Precipitates
Composite materials
Graphite
Powders
Toughness
Chemical reactions
Crack propagation
Cracks
X ray diffraction
Scanning electron microscopy
X-Ray Emission Spectrometry

Cite this

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abstract = "Structure and mechanical characteristics of dense ceramic composites synthesised by reactive hot pressing of TiC–B4C powder mixtures at 1800–1950°C under 30 MPa were investigated by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM and EDX). The results show that during hot pressing solid-phase chemical reaction 2TiC + B4C = 2TiB2 + 3C has occurred with final products like TiB2–TiC–C, TiB2–C or TiB2–B4C–C hetero-modulus composite formation with around one micrometer size carbon precipitates. The fracture toughness depends on the amount of graphite precipitation and has a distinct maximum K1C = 10 MPa m1/2 at nearly 7 vol.-{\%} of carbon precipitate. The fracture toughness behaviour is explained by the developed model of crack propagation. Within the model, it is shown that pores (voids) and low-modulus carbon inclusions blunt the cracks and can increase ceramic toughness in some cases.",
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Fracture toughness in some hetero-modulus composite carbides : carbon inclusions and voids. / Popov, O.; Vishnyakov, V.

In: Advances in Applied Ceramics, Vol. 116, No. 2, 2017, p. 61-70.

Research output: Contribution to journalArticle

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T2 - Advances in Applied Ceramics

AU - Popov, O.

AU - Vishnyakov, V.

PY - 2017

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N2 - Structure and mechanical characteristics of dense ceramic composites synthesised by reactive hot pressing of TiC–B4C powder mixtures at 1800–1950°C under 30 MPa were investigated by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM and EDX). The results show that during hot pressing solid-phase chemical reaction 2TiC + B4C = 2TiB2 + 3C has occurred with final products like TiB2–TiC–C, TiB2–C or TiB2–B4C–C hetero-modulus composite formation with around one micrometer size carbon precipitates. The fracture toughness depends on the amount of graphite precipitation and has a distinct maximum K1C = 10 MPa m1/2 at nearly 7 vol.-% of carbon precipitate. The fracture toughness behaviour is explained by the developed model of crack propagation. Within the model, it is shown that pores (voids) and low-modulus carbon inclusions blunt the cracks and can increase ceramic toughness in some cases.

AB - Structure and mechanical characteristics of dense ceramic composites synthesised by reactive hot pressing of TiC–B4C powder mixtures at 1800–1950°C under 30 MPa were investigated by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM and EDX). The results show that during hot pressing solid-phase chemical reaction 2TiC + B4C = 2TiB2 + 3C has occurred with final products like TiB2–TiC–C, TiB2–C or TiB2–B4C–C hetero-modulus composite formation with around one micrometer size carbon precipitates. The fracture toughness depends on the amount of graphite precipitation and has a distinct maximum K1C = 10 MPa m1/2 at nearly 7 vol.-% of carbon precipitate. The fracture toughness behaviour is explained by the developed model of crack propagation. Within the model, it is shown that pores (voids) and low-modulus carbon inclusions blunt the cracks and can increase ceramic toughness in some cases.

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