Head-to-tail and heteroleptic pentanuclear circular helicates

K.E. Allen, R.A. Faulkner, L.P. Harding, C.R. Rice, T. Riis-Johannessen, M.L. Voss, M. Whitehead

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N‐donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head‐to‐tail circular helicate, whereas reaction of two different ligands results in a heteroleptic pentanuclear circular helicate (see picture; green: Cu, red and blue: ligands).
LanguageEnglish
Pages6655-6658
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number37
DOIs
Publication statusPublished - Jul 2010

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abstract = "Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N‐donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head‐to‐tail circular helicate, whereas reaction of two different ligands results in a heteroleptic pentanuclear circular helicate (see picture; green: Cu, red and blue: ligands).",
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Head-to-tail and heteroleptic pentanuclear circular helicates. / Allen, K.E.; Faulkner, R.A.; Harding, L.P.; Rice, C.R.; Riis-Johannessen, T.; Voss, M.L.; Whitehead, M.

In: Angewandte Chemie - International Edition, Vol. 49, No. 37, 07.2010, p. 6655-6658.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Head-to-tail and heteroleptic pentanuclear circular helicates

AU - Allen, K.E.

AU - Faulkner, R.A.

AU - Harding, L.P.

AU - Rice, C.R.

AU - Riis-Johannessen, T.

AU - Voss, M.L.

AU - Whitehead, M.

N1 - cited By 24

PY - 2010/7

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AB - Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N‐donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head‐to‐tail circular helicate, whereas reaction of two different ligands results in a heteroleptic pentanuclear circular helicate (see picture; green: Cu, red and blue: ligands).

U2 - 10.1002/anie.201003342

DO - 10.1002/anie.201003342

M3 - Article

VL - 49

SP - 6655

EP - 6658

JO - Angewandte Chemie - International Edition

T2 - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

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ER -