Hypervalent Iodine Reagents by Anodic Oxidation: A Powerful Green Synthesis

Mohamed Elsherbini, Thomas Wirth

Research output: Contribution to journalReview article

11 Citations (Scopus)

Abstract

The anodic oxidation of aryl iodides is a powerful method for the synthesis of hypervalent iodine reagents, which eliminates the necessity to use expensive or hazardous chemical oxidizing reagents. The hypervalent iodine reagents generated at the anode are successfully used as either in‐cell or ex‐cell mediators for different valuable chemical transformations such as fluorinations and oxidative cyclizations. More recently, recyclable mediators and catalytic protocols have been developed.
LanguageEnglish
Pages13399-13407
Number of pages9
JournalChemistry - A European Journal
Volume24
Issue number51
Early online date14 Apr 2018
DOIs
Publication statusPublished - 12 Sep 2018
Externally publishedYes

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Anodic oxidation
Iodine
Fluorination
Cyclization
Hazardous Substances
Anodes
Iodides

Cite this

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Hypervalent Iodine Reagents by Anodic Oxidation : A Powerful Green Synthesis. / Elsherbini, Mohamed; Wirth, Thomas.

In: Chemistry - A European Journal, Vol. 24, No. 51, 12.09.2018, p. 13399-13407.

Research output: Contribution to journalReview article

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AU - Wirth, Thomas

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KW - Redox mediators

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