This study examines the impact of ice temperature on microwave emissivity over thin, newly formed sea ice at 6, 19, and 37 GHz during October 2003 in the southern Beaufort Sea, where the physical properties of newly formed sea ice were coincidently measured with microwave emissions. Six ice stations with distinct properties were selected and divided according to ice surface temperature into warm (above -3°C) or cold (below -3°C) stations. The warm stations had a lower emissivity at the vertical polarization by 0.1 than the cold stations and a corresponding difference in brine volume and dielectric properties. Significant correlations were observed between brine volume and ice emissivity (R2 = 0.8, p value < 0.05). A sensitivity study showed that decreasing ice temperatures from -2.1° to -5.0°C explained the observed difference of 0.1 in ice emissivity between warm and cold stations. The results suggest that the temperature of thin bare ice could be the critical factor in determining ice emissivity near the melting point (about -2°C). Furthermore, a slight decrease in ice temperature (i.e., from -2° to -5°C) significantly reduces the brine volume, thus resulting in high ice emissivity. Finally, we demonstrate the potential of newly formed ice to cause errors in estimating sea ice concentrations using Advanced Microwave Scanning Radiometer-E data.