Aerial ad-hoc networks have the potential to enable smart services while maintaining communication between the ground system and unmanned aerial vehicles (UAV). Previous research has focused on enabling aerial data-centric smart services while integrating the benefits of aerial objects such as UAVs in hostile and non-hostile environments. Quality of service (QoS) provisioning in UAV-assisted communication is a challenging research theme in aerial ad-hoc networks environments. Literature on aerial ad hoc networks lacks cooperative service-oriented modeling for distributed network environments, relying on costly static base station-oriented centralized network environments. Towards this end, this paper proposes a quality of service provisioning framework for a UAV-assisted aerial ad hoc network environment (QSPU) focusing on reliable aerial communication. The UAV’s aerial mobility and service parameters are modelled considering highly dynamic aerial ad-hoc environments. UAV-centric mobility models are utilized to develop a complete aerial routing framework. A comparative performance evaluation demonstrates the benefits of the proposed aerial communication framework. It is evident that QSPU outperforms the state-of-the-art techniques in terms of a number of service-oriented performance metrics in a UAV-assisted aerial ad-hoc network environment.