Iodoarene-Catalyzed Cyclizations of Unsaturated Amides

Ali Alhalib; Somaia Kamouka; Wesley J. Moran

doi:10.1021/acs.orglett.5b00333

Iodoarene-Catalyzed Cyclizations of Unsaturated Amides

Ali Alhalib, Somaia Kamouka, Wesley J. Moran

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79 Citations (Scopus)

Abstract

The cyclization of N-alkenylamides catalyzed by iodoarenes under oxidative conditions is presented. Five-, six-, and seven-membered rings with a range of substitutions can be prepared by this route. Preliminary data from the use of chiral iodoarenes as precatalysts show that enantiocontrol is feasible. © 2015 American Chemical Society.

Original language	English
Pages (from-to)	1453-1456
Number of pages	4
Journal	Organic Letters
Volume	17
Issue number	6
Early online date	5 Mar 2015
DOIs	https://doi.org/10.1021/acs.orglett.5b00333
Publication status	Published - 20 Mar 2015

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title = "Iodoarene-Catalyzed Cyclizations of Unsaturated Amides",

abstract = "The cyclization of N-alkenylamides catalyzed by iodoarenes under oxidative conditions is presented. Five-, six-, and seven-membered rings with a range of substitutions can be prepared by this route. Preliminary data from the use of chiral iodoarenes as precatalysts show that enantiocontrol is feasible. {\textcopyright} 2015 American Chemical Society.",

keywords = "unsaturated amides, Iodoarene",

author = "Ali Alhalib and Somaia Kamouka and Moran, {Wesley J.}",

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doi = "10.1021/acs.orglett.5b00333",

language = "English",

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T1 - Iodoarene-Catalyzed Cyclizations of Unsaturated Amides

AU - Alhalib, Ali

AU - Kamouka, Somaia

AU - Moran, Wesley J.

PY - 2015/3/20

Y1 - 2015/3/20

N2 - The cyclization of N-alkenylamides catalyzed by iodoarenes under oxidative conditions is presented. Five-, six-, and seven-membered rings with a range of substitutions can be prepared by this route. Preliminary data from the use of chiral iodoarenes as precatalysts show that enantiocontrol is feasible. © 2015 American Chemical Society.

AB - The cyclization of N-alkenylamides catalyzed by iodoarenes under oxidative conditions is presented. Five-, six-, and seven-membered rings with a range of substitutions can be prepared by this route. Preliminary data from the use of chiral iodoarenes as precatalysts show that enantiocontrol is feasible. © 2015 American Chemical Society.

KW - unsaturated amides

KW - Iodoarene

UR - http://www.scopus.com/inward/record.url?scp=84925349425&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.5b00333

DO - 10.1021/acs.orglett.5b00333

M3 - Article

VL - 17

SP - 1453

EP - 1456

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 6

ER -

Iodoarene-Catalyzed Cyclizations of Unsaturated Amides

Abstract

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