Iodoarene-Catalyzed Cyclizations of Unsaturated Amides

Ali Alhalib, Somaia Kamouka, Wesley J. Moran

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

The cyclization of N-alkenylamides catalyzed by iodoarenes under oxidative conditions is presented. Five-, six-, and seven-membered rings with a range of substitutions can be prepared by this route. Preliminary data from the use of chiral iodoarenes as precatalysts show that enantiocontrol is feasible. © 2015 American Chemical Society.
Original languageEnglish
Pages (from-to)1453-1456
Number of pages4
JournalOrganic Letters
Volume17
Issue number6
DOIs
Publication statusPublished - 20 Mar 2015

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Cyclization
Amides
amides
Substitution reactions
routes
substitutes
rings

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Alhalib, Ali ; Kamouka, Somaia ; Moran, Wesley J. / Iodoarene-Catalyzed Cyclizations of Unsaturated Amides. In: Organic Letters. 2015 ; Vol. 17, No. 6. pp. 1453-1456.
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Iodoarene-Catalyzed Cyclizations of Unsaturated Amides. / Alhalib, Ali; Kamouka, Somaia; Moran, Wesley J.

In: Organic Letters, Vol. 17, No. 6, 20.03.2015, p. 1453-1456.

Research output: Contribution to journalArticle

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AB - The cyclization of N-alkenylamides catalyzed by iodoarenes under oxidative conditions is presented. Five-, six-, and seven-membered rings with a range of substitutions can be prepared by this route. Preliminary data from the use of chiral iodoarenes as precatalysts show that enantiocontrol is feasible. © 2015 American Chemical Society.

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