Isolation and structural characterization of novel compounds containing B4O2 rings

Claire J. Carmalt, William Clegg, Alan H. Cowley, Fiona J. Lawlor, Todd B. Marder, Nicholas C. Norman, Craig R. Rice, Omar J. Sandoval, Andrew J. Scott

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Two compounds containing planar six-membered B4O2 rings have been synthesized and characterized by X-ray crystallography, namely [B4O2(OH)4] · [NH2Me2][Cl] and [B4O2(dab)2] (dab = 1,4-But-1,4-diazabutadiene), the former compound providing a model for one possible structure of boron monoxide. {BO}X.

LanguageEnglish
Pages2325-2328
Number of pages4
JournalPolyhedron
Volume16
Issue number13
DOIs
Publication statusPublished - 1997
Externally publishedYes

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Boron
X ray crystallography
crystallography
isolation
boron
rings
x rays

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Carmalt, C. J., Clegg, W., Cowley, A. H., Lawlor, F. J., Marder, T. B., Norman, N. C., ... Scott, A. J. (1997). Isolation and structural characterization of novel compounds containing B4O2 rings. Polyhedron, 16(13), 2325-2328. https://doi.org/10.1016/S0277-5387(96)00559-1
Carmalt, Claire J. ; Clegg, William ; Cowley, Alan H. ; Lawlor, Fiona J. ; Marder, Todd B. ; Norman, Nicholas C. ; Rice, Craig R. ; Sandoval, Omar J. ; Scott, Andrew J. / Isolation and structural characterization of novel compounds containing B4O2 rings. In: Polyhedron. 1997 ; Vol. 16, No. 13. pp. 2325-2328.
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abstract = "Two compounds containing planar six-membered B4O2 rings have been synthesized and characterized by X-ray crystallography, namely [B4O2(OH)4] · [NH2Me2][Cl] and [B4O2(dab)2] (dab = 1,4-But-1,4-diazabutadiene), the former compound providing a model for one possible structure of boron monoxide. {BO}X.",
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author = "Carmalt, {Claire J.} and William Clegg and Cowley, {Alan H.} and Lawlor, {Fiona J.} and Marder, {Todd B.} and Norman, {Nicholas C.} and Rice, {Craig R.} and Sandoval, {Omar J.} and Scott, {Andrew J.}",
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Carmalt, CJ, Clegg, W, Cowley, AH, Lawlor, FJ, Marder, TB, Norman, NC, Rice, CR, Sandoval, OJ & Scott, AJ 1997, 'Isolation and structural characterization of novel compounds containing B4O2 rings', Polyhedron, vol. 16, no. 13, pp. 2325-2328. https://doi.org/10.1016/S0277-5387(96)00559-1

Isolation and structural characterization of novel compounds containing B4O2 rings. / Carmalt, Claire J.; Clegg, William; Cowley, Alan H.; Lawlor, Fiona J.; Marder, Todd B.; Norman, Nicholas C.; Rice, Craig R.; Sandoval, Omar J.; Scott, Andrew J.

In: Polyhedron, Vol. 16, No. 13, 1997, p. 2325-2328.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Isolation and structural characterization of novel compounds containing B4O2 rings

AU - Carmalt, Claire J.

AU - Clegg, William

AU - Cowley, Alan H.

AU - Lawlor, Fiona J.

AU - Marder, Todd B.

AU - Norman, Nicholas C.

AU - Rice, Craig R.

AU - Sandoval, Omar J.

AU - Scott, Andrew J.

PY - 1997

Y1 - 1997

N2 - Two compounds containing planar six-membered B4O2 rings have been synthesized and characterized by X-ray crystallography, namely [B4O2(OH)4] · [NH2Me2][Cl] and [B4O2(dab)2] (dab = 1,4-But-1,4-diazabutadiene), the former compound providing a model for one possible structure of boron monoxide. {BO}X.

AB - Two compounds containing planar six-membered B4O2 rings have been synthesized and characterized by X-ray crystallography, namely [B4O2(OH)4] · [NH2Me2][Cl] and [B4O2(dab)2] (dab = 1,4-But-1,4-diazabutadiene), the former compound providing a model for one possible structure of boron monoxide. {BO}X.

KW - Boron

KW - Cyclic

KW - Diboron

KW - Inorganic ring

KW - Tetraboron

KW - X-ray

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U2 - 10.1016/S0277-5387(96)00559-1

DO - 10.1016/S0277-5387(96)00559-1

M3 - Article

VL - 16

SP - 2325

EP - 2328

JO - Polyhedron

T2 - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 13

ER -

Carmalt CJ, Clegg W, Cowley AH, Lawlor FJ, Marder TB, Norman NC et al. Isolation and structural characterization of novel compounds containing B4O2 rings. Polyhedron. 1997;16(13):2325-2328. https://doi.org/10.1016/S0277-5387(96)00559-1