Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

S. Bullock, A.J. Hallett, L.P. Harding, J.J. Higginson, S.A.F. Piela, S.J.A. Pope, C.R. Rice

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3′-diamino-2,2′-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.
Original languageEnglish
Pages (from-to)14690-14696
Number of pages7
JournalDalton Transactions
Volume41
Issue number48
DOIs
Publication statusPublished - Oct 2012

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Rhenium
Ketones
Steroids
Carbon Monoxide
Derivatives

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Bullock, S., Hallett, A. J., Harding, L. P., Higginson, J. J., Piela, S. A. F., Pope, S. J. A., & Rice, C. R. (2012). Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids. Dalton Transactions, 41(48), 14690-14696. https://doi.org/10.1039/c2dt31476b
Bullock, S. ; Hallett, A.J. ; Harding, L.P. ; Higginson, J.J. ; Piela, S.A.F. ; Pope, S.J.A. ; Rice, C.R. / Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids. In: Dalton Transactions. 2012 ; Vol. 41, No. 48. pp. 14690-14696.
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Bullock, S, Hallett, AJ, Harding, LP, Higginson, JJ, Piela, SAF, Pope, SJA & Rice, CR 2012, 'Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids', Dalton Transactions, vol. 41, no. 48, pp. 14690-14696. https://doi.org/10.1039/c2dt31476b

Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids. / Bullock, S.; Hallett, A.J.; Harding, L.P.; Higginson, J.J.; Piela, S.A.F.; Pope, S.J.A.; Rice, C.R.

In: Dalton Transactions, Vol. 41, No. 48, 10.2012, p. 14690-14696.

Research output: Contribution to journalArticle

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AB - A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3′-diamino-2,2′-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.

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