Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

S. Bullock, A.J. Hallett, L.P. Harding, J.J. Higginson, S.A.F. Piela, S.J.A. Pope, C.R. Rice

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15 Citations (Scopus)

Abstract

A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3′-diamino-2,2′-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.
Original languageEnglish
Pages (from-to)14690-14696
Number of pages7
JournalDalton Transactions
Volume41
Issue number48
DOIs
Publication statusPublished - Oct 2012

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    Bullock, S., Hallett, A. J., Harding, L. P., Higginson, J. J., Piela, S. A. F., Pope, S. J. A., & Rice, C. R. (2012). Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids. Dalton Transactions, 41(48), 14690-14696. https://doi.org/10.1039/c2dt31476b