Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

S. Bullock; A.J. Hallett; L.P. Harding; J.J. Higginson; S.A.F. Piela; S.J.A. Pope; C.R. Rice

doi:10.1039/c2dt31476b

Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

S. Bullock, A.J. Hallett, L.P. Harding, J.J. Higginson, S.A.F. Piela, S.J.A. Pope, C.R. Rice

Cardiff University

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3′-diamino-2,2′-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.

Original language	English
Pages (from-to)	14690-14696
Number of pages	7
Journal	Dalton Transactions
Volume	41
Issue number	48
DOIs	https://doi.org/10.1039/c2dt31476b
Publication status	Published - Oct 2012

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title = "Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids",

abstract = "A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3′-diamino-2,2′-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.",

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AU - Bullock, S.

AU - Hallett, A.J.

AU - Harding, L.P.

AU - Higginson, J.J.

AU - Piela, S.A.F.

AU - Pope, S.J.A.

AU - Rice, C.R.

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AB - A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3′-diamino-2,2′-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.

U2 - 10.1039/c2dt31476b

DO - 10.1039/c2dt31476b

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EP - 14696

JO - Dalton Transactions

JF - Dalton Transactions

IS - 48

ER -

Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

Abstract

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