Manganese, technetium and rhenium

Craig Rice

doi:10.1039/b410389k

Manganese, technetium and rhenium

Research output: Contribution to journal › Review article › peer-review

Abstract

As would be expected research into the Group 7 elements has focused on manganese. Much of this research deals with polynuclear compounds and their ability to act as single molecular magnets (SMMs). Notable examples are a new synthetic route to {Mn₁₂} complexes involving the reduction of Mn(VII) in alcohol/carboxylic acid media and the first example of an {Mn ₂} unit with SMM behaviour. Rhenium(I) carbonyl compounds continue to receive attention due their luminescent behaviour. Examples where the emission properties of the complex are altered upon formation of a pseudorotaxane or in the presence of anions are discussed.

Original language	English
Pages (from-to)	194-207
Number of pages	14
Journal	Annual Reports on the Progress of Chemistry - Section A
Volume	101
DOIs	https://doi.org/10.1039/b410389k
Publication status	Published - 2005

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10.1039/b410389k

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AB - As would be expected research into the Group 7 elements has focused on manganese. Much of this research deals with polynuclear compounds and their ability to act as single molecular magnets (SMMs). Notable examples are a new synthetic route to {Mn12} complexes involving the reduction of Mn(VII) in alcohol/carboxylic acid media and the first example of an {Mn 2} unit with SMM behaviour. Rhenium(I) carbonyl compounds continue to receive attention due their luminescent behaviour. Examples where the emission properties of the complex are altered upon formation of a pseudorotaxane or in the presence of anions are discussed.

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Manganese, technetium and rhenium

Abstract

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