Mechanistic insight into proton-coupled mixed valency

Luke A. Wilkinson; Kevin B. Vincent; Anthony J. H. M. Meijer; Nathan J. Patmore

doi:10.1039/C5CC07101A

Mechanistic insight into proton-coupled mixed valency

Luke A. Wilkinson, Kevin B. Vincent, Anthony J. H. M. Meijer, Nathan J. Patmore

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2 + (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s-1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET. © 2015 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	100-103
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	1
Early online date	19 Oct 2015
DOIs	https://doi.org/10.1039/C5CC07101A
Publication status	Published - 4 Jan 2016

Access to Document

10.1039/C5CC07101ALicence: Other

http://eprints.hud.ac.uk/id/eprint/28150/Licence: Unspecified

Cite this

@article{0598419394464ad6aa84df8cde32e24b,

title = "Mechanistic insight into proton-coupled mixed valency",

abstract = "Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2 + (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s-1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET. {\textcopyright} 2015 The Royal Society of Chemistry.",

author = "Wilkinson, {Luke A.} and Vincent, {Kevin B.} and Meijer, {Anthony J. H. M.} and Patmore, {Nathan J.}",

year = "2016",

month = jan,

day = "4",

doi = "10.1039/C5CC07101A",

language = "English",

volume = "52",

pages = "100--103",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Mechanistic insight into proton-coupled mixed valency

AU - Wilkinson, Luke A.

AU - Vincent, Kevin B.

AU - Meijer, Anthony J. H. M.

AU - Patmore, Nathan J.

PY - 2016/1/4

Y1 - 2016/1/4

N2 - Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2 + (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s-1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET. © 2015 The Royal Society of Chemistry.

AB - Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2 + (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s-1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET. © 2015 The Royal Society of Chemistry.

U2 - 10.1039/C5CC07101A

DO - 10.1039/C5CC07101A

M3 - Article

VL - 52

SP - 100

EP - 103

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 1

ER -

Mechanistic insight into proton-coupled mixed valency

Abstract

Access to Document

Fingerprint

Cite this