Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 100-103 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 52 |
| Issue number | 1 |
| Early online date | 19 Oct 2015 |
| DOIs | |
| Publication status | Published - 2016 |
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Mechanistic insight into proton-coupled mixed valency. / Wilkinson, Luke A.; Vincent, Kevin B.; Meijer, Anthony J. H. M.; Patmore, Nathan J.
In: Chemical Communications, Vol. 52, No. 1, 2016, p. 100-103.Research output: Contribution to journal › Article
TY - JOUR
T1 - Mechanistic insight into proton-coupled mixed valency
AU - Wilkinson, Luke A.
AU - Vincent, Kevin B.
AU - Meijer, Anthony J. H. M.
AU - Patmore, Nathan J.
PY - 2016
Y1 - 2016
N2 - Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2 + (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s-1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET. © 2015 The Royal Society of Chemistry.
AB - Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2 + (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s-1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET. © 2015 The Royal Society of Chemistry.
U2 - 10.1039/C5CC07101A
DO - 10.1039/C5CC07101A
M3 - Article
VL - 52
SP - 100
EP - 103
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 1
ER -