Mixed valency in hydrogen bonded 'dimers of dimers'

Luke A. Wilkinson; Laura McNeill; Anthony J H M Meijer; Nathan J. Patmore

doi:10.1021/ja312176x

Mixed valency in hydrogen bonded 'dimers of dimers'

Luke A. Wilkinson, Laura McNeill, Anthony J H M Meijer, Nathan J. Patmore

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Dimolybdenum quadruply bonded compounds containing a pendant lactam functional group form self-complementary hydrogen bonded 'dimers of dimers' in the solid-state and CH₂Cl₂ solutions. Electrochemical studies in CH₂Cl₂ show two consecutive one-electron redox processes corresponding to oxidation of the Mo₂ ⁴⁺ cores. Spectroelectrochemical studies on the 'dimers of dimers' show no evidence of intervalence charge transfer bands in the mixed valence radical cations formed by one-electron oxidation, indicating that they are examples of proton-coupled mixed valency.

Original language	English
Pages (from-to)	1723-1726
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	5
Early online date	21 Jan 2013
DOIs	https://doi.org/10.1021/ja312176x
Publication status	Published - 6 Feb 2013
Externally published	Yes

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abstract = "Dimolybdenum quadruply bonded compounds containing a pendant lactam functional group form self-complementary hydrogen bonded 'dimers of dimers' in the solid-state and CH2Cl2 solutions. Electrochemical studies in CH2Cl2 show two consecutive one-electron redox processes corresponding to oxidation of the Mo2 4+ cores. Spectroelectrochemical studies on the 'dimers of dimers' show no evidence of intervalence charge transfer bands in the mixed valence radical cations formed by one-electron oxidation, indicating that they are examples of proton-coupled mixed valency.",

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AU - Wilkinson, Luke A.

AU - McNeill, Laura

AU - Meijer, Anthony J H M

AU - Patmore, Nathan J.

PY - 2013/2/6

Y1 - 2013/2/6

N2 - Dimolybdenum quadruply bonded compounds containing a pendant lactam functional group form self-complementary hydrogen bonded 'dimers of dimers' in the solid-state and CH2Cl2 solutions. Electrochemical studies in CH2Cl2 show two consecutive one-electron redox processes corresponding to oxidation of the Mo2 4+ cores. Spectroelectrochemical studies on the 'dimers of dimers' show no evidence of intervalence charge transfer bands in the mixed valence radical cations formed by one-electron oxidation, indicating that they are examples of proton-coupled mixed valency.

AB - Dimolybdenum quadruply bonded compounds containing a pendant lactam functional group form self-complementary hydrogen bonded 'dimers of dimers' in the solid-state and CH2Cl2 solutions. Electrochemical studies in CH2Cl2 show two consecutive one-electron redox processes corresponding to oxidation of the Mo2 4+ cores. Spectroelectrochemical studies on the 'dimers of dimers' show no evidence of intervalence charge transfer bands in the mixed valence radical cations formed by one-electron oxidation, indicating that they are examples of proton-coupled mixed valency.

UR - https://www.scopus.com/pages/publications/84873328914

U2 - 10.1021/ja312176x

DO - 10.1021/ja312176x

M3 - Article

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SP - 1723

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 5

ER -

Mixed valency in hydrogen bonded 'dimers of dimers'

Abstract

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