Modelling of laser ablation and reactive oxygen plasmas for pulsed laser deposition of zinc oxide

S. Rajendiran, A. K. Rossall, Elizabeth A. Gibson, E. Wagenaars

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Pulsed laser deposition (PLD) in a low-pressure oxygen atmosphere is commonly used for the production of high-quality, stoichiometric zinc oxide thin films. An alternative approach that has the potential benefit of increased process control is plasma-enhanced PLD, i.e. the use of a low-temperature oxygen plasma instead of a neutral gas. So far, the development of PE-PLD, and PLD in general, has been hampered by a lack of detailed understanding of the underpinning physics and chemistry. In this paper, we present modelling investigations aimed at further developing such understanding. Two-dimensional modelling of an inductively-coupled radio-frequency oxygen plasma showed that densities of 1014-1015cm-3 of reactive oxygen species O and O2* can be produced for operating pressures between 3 and 100Pa. Together with the absolute densities of species, also the ratio between different reactive species, e.g. O and O2*, can be controlled by changing the operating pressure. Both can be used to find the optimum conditions for stoichiometric zinc oxide thin film deposition. Additionally, we investigated laser ablation of zinc using a different two-dimensional hydrodynamic code (POLLUX). This showed that the amount of material that is ablated increases from 2.9 to 4.7μg per pulse for laser fluences from 2 to 10J/cm2. However, the increased laser fluence also results in an increased average ionisation of the plasma plume, from 3.4 to 5.6 over the same fluence range, which is likely to influence the chemistry near the deposition substrate and consequently the film quality.

LanguageEnglish
Pages417-423
Number of pages7
JournalSurface and Coatings Technology
Volume260
Early online date22 Jul 2014
DOIs
Publication statusPublished - 15 Dec 2014
Externally publishedYes

Fingerprint

Zinc Oxide
oxygen plasma
Laser ablation
Pulsed laser deposition
Zinc oxide
zinc oxides
laser ablation
pulsed laser deposition
Oxygen
Plasmas
fluence
Oxide films
chemistry
Thin films
Lasers
neutral gases
oxygen
cold plasmas
thin films
Ionization

Cite this

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abstract = "Pulsed laser deposition (PLD) in a low-pressure oxygen atmosphere is commonly used for the production of high-quality, stoichiometric zinc oxide thin films. An alternative approach that has the potential benefit of increased process control is plasma-enhanced PLD, i.e. the use of a low-temperature oxygen plasma instead of a neutral gas. So far, the development of PE-PLD, and PLD in general, has been hampered by a lack of detailed understanding of the underpinning physics and chemistry. In this paper, we present modelling investigations aimed at further developing such understanding. Two-dimensional modelling of an inductively-coupled radio-frequency oxygen plasma showed that densities of 1014-1015cm-3 of reactive oxygen species O and O2* can be produced for operating pressures between 3 and 100Pa. Together with the absolute densities of species, also the ratio between different reactive species, e.g. O and O2*, can be controlled by changing the operating pressure. Both can be used to find the optimum conditions for stoichiometric zinc oxide thin film deposition. Additionally, we investigated laser ablation of zinc using a different two-dimensional hydrodynamic code (POLLUX). This showed that the amount of material that is ablated increases from 2.9 to 4.7μg per pulse for laser fluences from 2 to 10J/cm2. However, the increased laser fluence also results in an increased average ionisation of the plasma plume, from 3.4 to 5.6 over the same fluence range, which is likely to influence the chemistry near the deposition substrate and consequently the film quality.",
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Modelling of laser ablation and reactive oxygen plasmas for pulsed laser deposition of zinc oxide. / Rajendiran, S.; Rossall, A. K.; Gibson, Elizabeth A.; Wagenaars, E.

In: Surface and Coatings Technology, Vol. 260, 15.12.2014, p. 417-423.

Research output: Contribution to journalArticle

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T1 - Modelling of laser ablation and reactive oxygen plasmas for pulsed laser deposition of zinc oxide

AU - Rajendiran, S.

AU - Rossall, A. K.

AU - Gibson, Elizabeth A.

AU - Wagenaars, E.

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