Nanoparticle ejection from gold during ion irradiation

R. C. Birtcher, S. E. Donnelly, S. Schlutig

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

We have used in situ transmission electron microscopy to study the sputtering of gold by inert-gas ions and, in particular, nanoparticles ejected by individual ion impacts. Irradiations were performed at room temperature in transmission geometry with Ne, Ar, Kr and Xe ions at energies between 100 and 600 keV. Nanoparticles result from situations in which ion impacts also give rise to nanometer size craters on the surface. The number of nanoparticles increased linearly with increasing ion dose. The rate of nanoparticle ejection scales with the probability, calculated with standard Monte Carlo techniques, for high-energy deposition events by individual ions in the near-surface region regardless of the irradiation. The percentage of near-surface, high-energy recoils that eject a nanoparticle is high. The rate of nanoparticle ejection depends on energy transfer to the Au lattice and not on the ion that makes the impact or its energy. Ejected nanoparticles account for the nonlinear component of sputtering. Monte Carlo calculations offer a general technique for predicting situations in which nanoparticles can be ejected and thus when the nonlinear contribution to the sputtering yield is likely to be significant.

Original languageEnglish
Pages (from-to)69-75
Number of pages7
JournalNuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
Volume215
Issue number1-2
Early online date23 Jul 2003
DOIs
Publication statusPublished - 1 Jan 2004
Externally publishedYes

Fingerprint

Ion bombardment
ion irradiation
ejection
Gold
gold
Nanoparticles
nanoparticles
Ions
Sputtering
ion impact
sputtering
ions
Irradiation
Noble Gases
irradiation
energy
Inert gases
craters
Energy transfer
rare gases

Cite this

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Nanoparticle ejection from gold during ion irradiation. / Birtcher, R. C.; Donnelly, S. E.; Schlutig, S.

In: Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, Vol. 215, No. 1-2, 01.01.2004, p. 69-75.

Research output: Contribution to journalArticle

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AU - Donnelly, S. E.

AU - Schlutig, S.

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