Observation of an Inversion in Photophysical Tuning in a Systematic Study of Luminescent Triazole-Based Osmium(II) Complexes

Physics & Astronomy

• osmium 100%
• ligands 71%
• pyrazines 68%
• molecular orbitals 64%
• inversions 57%
• tuning 53%
• pyridines 44%
• stabilization 34%
• red shift 24%
• blue shift 18%
• optical absorption 9%
• rings 8%
• phosphorescence 7%
• shift 7%
• phenyls 6%
• metals 5%
• light emission 5%
• charge transfer 5%
• absorption spectra 4%
• oxidation 4%
• optical properties 3%

Chemistry

• Pyrazine 78%
• Emission Maxima 59%
• Luminiscence Type 49%
• Lowest Unoccupied Molecular Orbital 40%
• Highest Occupied Molecular Orbital 29%
• Ligand 27%
• Pyridine 25%
• Red 24%
• Donor 24%
• Blue 19%
• Pyridine Ring 19%
• Absorptivity 16%
• Molecular Orbital 16%
• Triazole 9%
• Oxidation Potential 9%
• Phosphorescence 9%
• Reduction Potential 9%
• NIR Spectroscopy 8%
• Absorption Maxima 8%
• Orange 7%
• Band Gap 6%
• Optical Property 6%