Octapi interactions:: Self-assembly of a Pd-based [2]catenane driven by eightfold π interactions

J. Lu; D.R. Turner; L.P. Harding; L.T. Byrne; M.V. Baker; S.R. Batten

doi:10.1021/ja9041912

Octapi interactions: Self-assembly of a Pd-based [2]catenane driven by eightfold π interactions

J. Lu, D.R. Turner, L.P. Harding, L.T. Byrne, M.V. Baker, S.R. Batten

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

An unprecedented 2.5 nm array of π interactions between eight aromatic rings drives the formation of a [2]catenane. Disruption of this array through the use of longer ligands results in the formation of only single, uncatenated rings. The catenated complex is shown to persist in solution alongside its constituent metallomacrocycles.

Original language	English
Pages (from-to)	10372-10373
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	30
DOIs	https://doi.org/10.1021/ja9041912
Publication status	Published - Jul 2009

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title = "Octapi interactions:: Self-assembly of a Pd-based [2]catenane driven by eightfold π interactions",

abstract = "An unprecedented 2.5 nm array of π interactions between eight aromatic rings drives the formation of a [2]catenane. Disruption of this array through the use of longer ligands results in the formation of only single, uncatenated rings. The catenated complex is shown to persist in solution alongside its constituent metallomacrocycles.",

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AU - Lu, J.

AU - Turner, D.R.

AU - Harding, L.P.

AU - Byrne, L.T.

AU - Baker, M.V.

AU - Batten, S.R.

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AB - An unprecedented 2.5 nm array of π interactions between eight aromatic rings drives the formation of a [2]catenane. Disruption of this array through the use of longer ligands results in the formation of only single, uncatenated rings. The catenated complex is shown to persist in solution alongside its constituent metallomacrocycles.

U2 - 10.1021/ja9041912

DO - 10.1021/ja9041912

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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IS - 30

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Octapi interactions: Self-assembly of a Pd-based [2]catenane driven by eightfold π interactions

Abstract

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