Abstract
We show that optical excitation of radical triplet pair systems can produce a fourfold NMR signal enhancement in solution, without the need for microwave pumping. Development of optical hyperpolarization methods will significantly impact all NMR user groups by boosting sensitivity and reducing signal averaging times.
| Language | English |
|---|---|
| Pages | 13221-13224 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 52 |
| Issue number | 90 |
| Early online date | 30 Sep 2016 |
| DOIs | |
| Publication status | Published - 2016 |
| Externally published | Yes |
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Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy. / Dale, Matthew W.; Wedge, Christopher J.
In: Chemical Communications, Vol. 52, No. 90, 2016, p. 13221-13224.Research output: Contribution to journal › Article
TY - JOUR
T1 - Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy
AU - Dale, Matthew W.
AU - Wedge, Christopher J.
PY - 2016
Y1 - 2016
N2 - We show that optical excitation of radical triplet pair systems can produce a fourfold NMR signal enhancement in solution, without the need for microwave pumping. Development of optical hyperpolarization methods will significantly impact all NMR user groups by boosting sensitivity and reducing signal averaging times.
AB - We show that optical excitation of radical triplet pair systems can produce a fourfold NMR signal enhancement in solution, without the need for microwave pumping. Development of optical hyperpolarization methods will significantly impact all NMR user groups by boosting sensitivity and reducing signal averaging times.
UR - http://www.scopus.com/inward/record.url?scp=84994673973&partnerID=8YFLogxK
U2 - 10.1039/c6cc06651h
DO - 10.1039/c6cc06651h
M3 - Article
VL - 52
SP - 13221
EP - 13224
JO - Chemical Communications
T2 - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 90
ER -