Oxidative Rearrangement of Tertiary Propargylic Alcohols

Arantxa Rodríguez, Wesley J. Moran

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

An oxidative rearrangement of tertiary alcohols mediated by m-CPBA is described that generates tetrasubstituted alkenes with a carboxylic acid substituent. The mechanism of the reaction is proposed to proceed through epoxidation of the alkyne to form an oxirene that undergoes a 1,2-aryl shift.

LanguageEnglish
Pages102-104
Number of pages3
JournalSynlett
Volume24
Issue number1
DOIs
Publication statusPublished - Jan 2013

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Alkynes
Epoxidation
Alkenes
Carboxylic Acids
Alcohols
3-chloroperbenzoic acid
oxirene

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Rodríguez, Arantxa ; Moran, Wesley J. / Oxidative Rearrangement of Tertiary Propargylic Alcohols. In: Synlett. 2013 ; Vol. 24, No. 1. pp. 102-104.
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Oxidative Rearrangement of Tertiary Propargylic Alcohols. / Rodríguez, Arantxa; Moran, Wesley J.

In: Synlett, Vol. 24, No. 1, 01.2013, p. 102-104.

Research output: Contribution to journalArticle

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