Oxide glass structure evolution under swift heavy ion irradiation

Christian Mendoza-Mujica; S. Peuget; T. Charpentier; M. Moskura; R. Caraballo; O. Bouty; A.h. Mir; I. Monnet; C. Grygiel; C. Jegou

doi:10.1016/j.nimb.2014.02.002

Oxide glass structure evolution under swift heavy ion irradiation

Christian Mendoza-Mujica, S. Peuget, T. Charpentier, M. Moskura, R. Caraballo, O. Bouty, A.h. Mir, I. Monnet, C. Grygiel, C. Jegou

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49 Citations (Scopus)

Abstract

The effects of ion tracks on the structure of oxide glasses were examined by irradiating a silica glass and two borosilicate glass specimens containing 3 and 6 oxides with krypton ions (74 MeV) and xenon ions (92 MeV). Structural changes in the glass were observed by Raman and nuclear magnetic resonance spectroscopy using a multinuclear approach (11B, 23Na, 27Al and 29Si). The structure of irradiated silica glass resembles a structure quenched at very high temperature. Both borosilicate glass specimens exhibited depolymerization of the borosilicate network, a lower boron coordination number, and a change in the role of a fraction of the sodium atoms after irradiation, suggesting that the final borosilicate glass structures were quenched from a high temperature state. In addition, a sharp increase in the concentration of three membered silica rings and the presence of large amounts of penta- and hexacoordinate aluminum in the irradiated 6-oxide glass suggest that the irradiated glass is different from a liquid quenched at equilibrium, but it is rather obtained from a nonequilibrium liquid that is partially relaxed by very rapid quenching within the ion tracks.

Original language	English
Pages (from-to)	54-65
Number of pages	12
Journal	Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
Volume	325
Early online date	5 Mar 2014
DOIs	https://doi.org/10.1016/j.nimb.2014.02.002
Publication status	Published - 15 Apr 2014
Externally published	Yes

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Mendoza-Mujica, C., Peuget, S., Charpentier, T., Moskura, M., Caraballo, R., Bouty, O., Mir, A. H., Monnet, I., Grygiel, C., & Jegou, C. (2014). Oxide glass structure evolution under swift heavy ion irradiation. Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, 325, 54-65. https://doi.org/10.1016/j.nimb.2014.02.002

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title = "Oxide glass structure evolution under swift heavy ion irradiation",

abstract = "The effects of ion tracks on the structure of oxide glasses were examined by irradiating a silica glass and two borosilicate glass specimens containing 3 and 6 oxides with krypton ions (74 MeV) and xenon ions (92 MeV). Structural changes in the glass were observed by Raman and nuclear magnetic resonance spectroscopy using a multinuclear approach (11B, 23Na, 27Al and 29Si). The structure of irradiated silica glass resembles a structure quenched at very high temperature. Both borosilicate glass specimens exhibited depolymerization of the borosilicate network, a lower boron coordination number, and a change in the role of a fraction of the sodium atoms after irradiation, suggesting that the final borosilicate glass structures were quenched from a high temperature state. In addition, a sharp increase in the concentration of three membered silica rings and the presence of large amounts of penta- and hexacoordinate aluminum in the irradiated 6-oxide glass suggest that the irradiated glass is different from a liquid quenched at equilibrium, but it is rather obtained from a nonequilibrium liquid that is partially relaxed by very rapid quenching within the ion tracks.",

keywords = "silica glass, Borosilicate glasses, borosilicate, Irradiation, swift heavy ions, ion tracks",

author = "Christian Mendoza-Mujica and S. Peuget and T. Charpentier and M. Moskura and R. Caraballo and O. Bouty and A.h. Mir and I. Monnet and C. Grygiel and C. Jegou",

note = "Changed to 'Entry in Progress' as no authors are affiliated to Huddersfield on the output. SH 2/8/17 No full text in Eprints. HN 23/11/2017",

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Mendoza-Mujica, C, Peuget, S, Charpentier, T, Moskura, M, Caraballo, R, Bouty, O, Mir, AH, Monnet, I, Grygiel, C & Jegou, C 2014, 'Oxide glass structure evolution under swift heavy ion irradiation', Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, vol. 325, pp. 54-65. https://doi.org/10.1016/j.nimb.2014.02.002

TY - JOUR

T1 - Oxide glass structure evolution under swift heavy ion irradiation

AU - Mendoza-Mujica, Christian

AU - Peuget, S.

AU - Charpentier, T.

AU - Moskura, M.

AU - Caraballo, R.

AU - Bouty, O.

AU - Mir, A.h.

AU - Monnet, I.

AU - Grygiel, C.

AU - Jegou, C.

N1 - Changed to 'Entry in Progress' as no authors are affiliated to Huddersfield on the output. SH 2/8/17 No full text in Eprints. HN 23/11/2017

PY - 2014/4/15

Y1 - 2014/4/15

N2 - The effects of ion tracks on the structure of oxide glasses were examined by irradiating a silica glass and two borosilicate glass specimens containing 3 and 6 oxides with krypton ions (74 MeV) and xenon ions (92 MeV). Structural changes in the glass were observed by Raman and nuclear magnetic resonance spectroscopy using a multinuclear approach (11B, 23Na, 27Al and 29Si). The structure of irradiated silica glass resembles a structure quenched at very high temperature. Both borosilicate glass specimens exhibited depolymerization of the borosilicate network, a lower boron coordination number, and a change in the role of a fraction of the sodium atoms after irradiation, suggesting that the final borosilicate glass structures were quenched from a high temperature state. In addition, a sharp increase in the concentration of three membered silica rings and the presence of large amounts of penta- and hexacoordinate aluminum in the irradiated 6-oxide glass suggest that the irradiated glass is different from a liquid quenched at equilibrium, but it is rather obtained from a nonequilibrium liquid that is partially relaxed by very rapid quenching within the ion tracks.

AB - The effects of ion tracks on the structure of oxide glasses were examined by irradiating a silica glass and two borosilicate glass specimens containing 3 and 6 oxides with krypton ions (74 MeV) and xenon ions (92 MeV). Structural changes in the glass were observed by Raman and nuclear magnetic resonance spectroscopy using a multinuclear approach (11B, 23Na, 27Al and 29Si). The structure of irradiated silica glass resembles a structure quenched at very high temperature. Both borosilicate glass specimens exhibited depolymerization of the borosilicate network, a lower boron coordination number, and a change in the role of a fraction of the sodium atoms after irradiation, suggesting that the final borosilicate glass structures were quenched from a high temperature state. In addition, a sharp increase in the concentration of three membered silica rings and the presence of large amounts of penta- and hexacoordinate aluminum in the irradiated 6-oxide glass suggest that the irradiated glass is different from a liquid quenched at equilibrium, but it is rather obtained from a nonequilibrium liquid that is partially relaxed by very rapid quenching within the ion tracks.

KW - silica glass

KW - Borosilicate glasses

KW - borosilicate

KW - Irradiation

KW - swift heavy ions

KW - ion tracks

UR - https://www.scopus.com/pages/publications/84896758174

U2 - 10.1016/j.nimb.2014.02.002

DO - 10.1016/j.nimb.2014.02.002

M3 - Article

SN - 0168-583X

VL - 325

SP - 54

EP - 65

JO - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

JF - Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

ER -

Oxide glass structure evolution under swift heavy ion irradiation

Abstract

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