Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration

Tamara Fulgheri, Philip Cornwall, Andrew R. Turner, Joseph B. Sweeney, Duncan M. Gill

Research output: Contribution to journalArticle

Abstract

We report parallel kinetic resolution of intramolecular Diels-Alder cycloadducts, where up to five stereocentres are defined using asymmetric hydroboration as the enantiodiscriminating reaction, and reveal evidence for dynamic kinetic resolution based on a reversible cycloaddition.

Original languageEnglish
Pages (from-to)7223-7227
Number of pages5
JournalEuropean Journal of Organic Chemistry
Volume2019
Issue number43
Early online date18 Oct 2019
DOIs
Publication statusPublished - 24 Nov 2019

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