Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

Christine E. Welby; Georgina K. Armitage; Harry Bartley; Alessandro Sinopoli; Baljinder S. Uppal; Paul I P Elliott

doi:10.1039/c3pp50437a

Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

Christine E. Welby, Georgina K. Armitage, Harry Bartley, Alessandro Sinopoli, Baljinder S. Uppal, Paul I P Elliott

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Complexes of the form [Ru(diimine)₂(btz)]²⁺ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine) ₂(solvent)₂]²⁺. This journal is

Original language	English
Pages (from-to)	735-738
Number of pages	4
Journal	Photochemical and Photobiological Sciences
Volume	13
Issue number	5
DOIs	https://doi.org/10.1039/c3pp50437a
Publication status	Published - 1 May 2014

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title = "Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes",

abstract = "Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine) 2(solvent)2]2+. This journal is",

keywords = "Ligands, Molecular structure, Organometallic Compounds, Photochemical Processes, Ruthenium",

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year = "2014",

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doi = "10.1039/c3pp50437a",

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T1 - Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

AU - Welby, Christine E.

AU - Armitage, Georgina K.

AU - Bartley, Harry

AU - Sinopoli, Alessandro

AU - Uppal, Baljinder S.

AU - Elliott, Paul I P

PY - 2014/5/1

Y1 - 2014/5/1

N2 - Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine) 2(solvent)2]2+. This journal is

AB - Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine) 2(solvent)2]2+. This journal is

KW - Ligands

KW - Molecular structure

KW - Organometallic Compounds

KW - Photochemical Processes

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/84898823331

U2 - 10.1039/c3pp50437a

DO - 10.1039/c3pp50437a

M3 - Article

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AN - SCOPUS:84898823331

SN - 1474-905X

VL - 13

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EP - 738

JO - Photochemical and Photobiological Sciences

JF - Photochemical and Photobiological Sciences

IS - 5

ER -

Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

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