TY - JOUR
T1 - Photophysics and photochemistry of 1,2,3-triazole-based complexes
AU - Scattergood, Paul
AU - Sinopoli, Alessandro
AU - Elliott, Paul
PY - 2017/11
Y1 - 2017/11
N2 - The copper-catalysed cycloaddition of alkynes and azides to form 1,2,3-triazoles has emerged as a powerful tool in ligand design and the synthesis of novel transition metal complexes. In this review we focus on the photophysical properties of metal complexes bearing 1,2,3-triazole-based ligands with a particular emphasis on those of d6 metals including rhenium(I), iron(II), ruthenium(II), osmium(II) and iridium(III). We also highlight key examples of triazole complexes of platinum(II) and palladium(II) as well as the lanthanides and coinage metals.
AB - The copper-catalysed cycloaddition of alkynes and azides to form 1,2,3-triazoles has emerged as a powerful tool in ligand design and the synthesis of novel transition metal complexes. In this review we focus on the photophysical properties of metal complexes bearing 1,2,3-triazole-based ligands with a particular emphasis on those of d6 metals including rhenium(I), iron(II), ruthenium(II), osmium(II) and iridium(III). We also highlight key examples of triazole complexes of platinum(II) and palladium(II) as well as the lanthanides and coinage metals.
UR - http://www.sciencedirect.com/science/journal/00108545
U2 - 10.1016/j.ccr.2017.06.017
DO - 10.1016/j.ccr.2017.06.017
M3 - Article
VL - 350
SP - 136
EP - 154
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
ER -
