Photophysics and photochemistry of 1,2,3-triazole-based complexes

Paul Scattergood, Alessandro Sinopoli, Paul Elliott

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

The copper-catalysed cycloaddition of alkynes and azides to form 1,2,3-triazoles has emerged as a powerful tool in ligand design and the synthesis of novel transition metal complexes. In this review we focus on the photophysical properties of metal complexes bearing 1,2,3-triazole-based ligands with a particular emphasis on those of d6 metals including rhenium(I), iron(II), ruthenium(II), osmium(II) and iridium(III). We also highlight key examples of triazole complexes of platinum(II) and palladium(II) as well as the lanthanides and coinage metals.
Original languageEnglish
Pages (from-to)136-154
Number of pages19
JournalCoordination Chemistry Reviews
Volume350
Early online date26 Jul 2017
DOIs
Publication statusPublished - Nov 2017

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Triazoles
Photochemical reactions
Iron
Coordination Complexes
Bearings (structural)
Coinage
Metals
Rhenium
Ligands
Osmium
Iridium
Lanthanoid Series Elements
Alkynes
Ruthenium
Azides
Cycloaddition
Palladium
Platinum
Transition metals
Copper

Cite this

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abstract = "The copper-catalysed cycloaddition of alkynes and azides to form 1,2,3-triazoles has emerged as a powerful tool in ligand design and the synthesis of novel transition metal complexes. In this review we focus on the photophysical properties of metal complexes bearing 1,2,3-triazole-based ligands with a particular emphasis on those of d6 metals including rhenium(I), iron(II), ruthenium(II), osmium(II) and iridium(III). We also highlight key examples of triazole complexes of platinum(II) and palladium(II) as well as the lanthanides and coinage metals.",
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Photophysics and photochemistry of 1,2,3-triazole-based complexes. / Scattergood, Paul; Sinopoli, Alessandro; Elliott, Paul.

In: Coordination Chemistry Reviews, Vol. 350, 11.2017, p. 136-154.

Research output: Contribution to journalArticle

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