Platinum Catalysed Diboration of Terminal Alkenes with Chiral Diborane(4) Compounds

Todd B. Marder, Nicholas C. Norman, Craig R. Rice

Research output: Contribution to journalArticle

83 Citations (Scopus)

Abstract

Chiral diborane(4) compounds, synthesised from B2(NMe2)4 and the relevant chiral diols, react with terminal alkenes in the presence of Pt(dba)2 (dba = dibenzylidene acetone) affording 1,2-diboryl compounds which have diastereoselectivities up to 60% d.e.

LanguageEnglish
Pages155-158
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number1-2
DOIs
Publication statusPublished - 1 Jan 1998
Externally publishedYes

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Alkenes
Platinum
dibenzylidene acetone
diborane

Cite this

Marder, Todd B. ; Norman, Nicholas C. ; Rice, Craig R. / Platinum Catalysed Diboration of Terminal Alkenes with Chiral Diborane(4) Compounds. In: Tetrahedron Letters. 1998 ; Vol. 39, No. 1-2. pp. 155-158.
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Platinum Catalysed Diboration of Terminal Alkenes with Chiral Diborane(4) Compounds. / Marder, Todd B.; Norman, Nicholas C.; Rice, Craig R.

In: Tetrahedron Letters, Vol. 39, No. 1-2, 01.01.1998, p. 155-158.

Research output: Contribution to journalArticle

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