Platinum-catalysed synthesis of trichloroamidines

Jay J. Dunsford; Jason E. Camp

doi:10.1016/j.tetlet.2013.06.062

Platinum-catalysed synthesis of trichloroamidines

Jay J. Dunsford, Jason E. Camp

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A mild platinum-catalysed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesised via the direct reaction of amines and halogenated nitriles.

Original language	English
Pages (from-to)	4522-4523
Number of pages	2
Journal	Tetrahedron Letters
Volume	54
Issue number	34
Early online date	22 Jun 2013
DOIs	https://doi.org/10.1016/j.tetlet.2013.06.062
Publication status	Published - 21 Aug 2013
Externally published	Yes

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Cite this

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title = "Platinum-catalysed synthesis of trichloroamidines",

abstract = "A mild platinum-catalysed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesised via the direct reaction of amines and halogenated nitriles.",

keywords = "Amidine, Nitrile activation, Platinum catalysis",

author = "Dunsford, {Jay J.} and Camp, {Jason E.}",

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AU - Dunsford, Jay J.

AU - Camp, Jason E.

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N2 - A mild platinum-catalysed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesised via the direct reaction of amines and halogenated nitriles.

AB - A mild platinum-catalysed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesised via the direct reaction of amines and halogenated nitriles.

KW - Amidine

KW - Nitrile activation

KW - Platinum catalysis

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UR - https://www.journals.elsevier.com/tetrahedron-letters

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DO - 10.1016/j.tetlet.2013.06.062

M3 - Article

AN - SCOPUS:84880282726

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EP - 4523

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 34

ER -

Platinum-catalysed synthesis of trichloroamidines

Abstract

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