Platinum-catalysed synthesis of trichloroamidines

Jay J. Dunsford, Jason E. Camp

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A mild platinum-catalysed method for the formation of free amidines from the reaction of amines and trichloroacetonitrile in nonpolar solvents has been developed. This protocol provides access to novel amidines that in some cases (4b-d) cannot be synthesised via the direct reaction of amines and halogenated nitriles.

LanguageEnglish
Pages4522-4523
Number of pages2
JournalTetrahedron Letters
Volume54
Issue number34
Early online date22 Jun 2013
DOIs
Publication statusPublished - 21 Aug 2013
Externally publishedYes

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Amidines
Platinum
Amines
Nitriles
trichloroacetonitrile

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Dunsford, Jay J. ; Camp, Jason E. / Platinum-catalysed synthesis of trichloroamidines. In: Tetrahedron Letters. 2013 ; Vol. 54, No. 34. pp. 4522-4523.
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Platinum-catalysed synthesis of trichloroamidines. / Dunsford, Jay J.; Camp, Jason E.

In: Tetrahedron Letters, Vol. 54, No. 34, 21.08.2013, p. 4522-4523.

Research output: Contribution to journalArticle

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