[(PPH3)Ag(HCB11Me11)]

A complex with intermolecular Ag⋯H3C interactions

Michael J. Ingleson, Mary F. Mahon, Nathan J. Patmore, Giuseppe D. Ruggiero, Andrew S. Weller

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

Both in the solid state and in solution, the complex, [(PPh3)Ag(HCB11Me11)] displays significant intermolecular Ag ⋯ H3C interactions. This complex serves as a model for the interaction between a d10 metal center and an alkane.

Original languageEnglish
Pages (from-to)3694-3697
Number of pages4
JournalAngewandte Chemie - International Edition
Volume41
Issue number19
DOIs
Publication statusPublished - 4 Oct 2002
Externally publishedYes

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Alkanes
Paraffins
Metals

Cite this

Ingleson, Michael J. ; Mahon, Mary F. ; Patmore, Nathan J. ; Ruggiero, Giuseppe D. ; Weller, Andrew S. / [(PPH3)Ag(HCB11Me11)] : A complex with intermolecular Ag⋯H3C interactions. In: Angewandte Chemie - International Edition. 2002 ; Vol. 41, No. 19. pp. 3694-3697.
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[(PPH3)Ag(HCB11Me11)] : A complex with intermolecular Ag⋯H3C interactions. / Ingleson, Michael J.; Mahon, Mary F.; Patmore, Nathan J.; Ruggiero, Giuseppe D.; Weller, Andrew S.

In: Angewandte Chemie - International Edition, Vol. 41, No. 19, 04.10.2002, p. 3694-3697.

Research output: Contribution to journalArticle

TY - JOUR

T1 - [(PPH3)Ag(HCB11Me11)]

T2 - A complex with intermolecular Ag⋯H3C interactions

AU - Ingleson, Michael J.

AU - Mahon, Mary F.

AU - Patmore, Nathan J.

AU - Ruggiero, Giuseppe D.

AU - Weller, Andrew S.

PY - 2002/10/4

Y1 - 2002/10/4

N2 - Both in the solid state and in solution, the complex, [(PPh3)Ag(HCB11Me11)] displays significant intermolecular Ag ⋯ H3C interactions. This complex serves as a model for the interaction between a d10 metal center and an alkane.

AB - Both in the solid state and in solution, the complex, [(PPh3)Ag(HCB11Me11)] displays significant intermolecular Ag ⋯ H3C interactions. This complex serves as a model for the interaction between a d10 metal center and an alkane.

KW - Anions

KW - C-H activation

KW - Carboranes

KW - Phosphane ligands

KW - Silver

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U2 - 10.1002/1521-3773(20021004)41:19<3694::AID-ANIE3694>3.0.CO;2-B

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EP - 3697

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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