[(PPH3)Ag(HCB11Me11)]: A complex with intermolecular Ag⋯H3C interactions

Michael J. Ingleson; Mary F. Mahon; Nathan J. Patmore; Giuseppe D. Ruggiero; Andrew S. Weller

doi:10.1002/1521-3773(20021004)41:19<3694::AID-ANIE3694>3.0.CO;2-B

[(PPH₃)Ag(HCB₁₁Me₁₁)]: A complex with intermolecular Ag⋯H₃C interactions

Michael J. Ingleson, Mary F. Mahon, Nathan J. Patmore, Giuseppe D. Ruggiero, Andrew S. Weller

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Both in the solid state and in solution, the complex, [(PPh₃)Ag(HCB₁₁Me₁₁)] displays significant intermolecular Ag ⋯ H₃C interactions. This complex serves as a model for the interaction between a d¹⁰ metal center and an alkane.

Original language	English
Pages (from-to)	3694-3697
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	19
DOIs	https://doi.org/10.1002/1521-3773(20021004)41:19<3694::AID-ANIE3694>3.0.CO;2-B
Publication status	Published - 4 Oct 2002
Externally published	Yes

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10.1002/1521-3773(20021004)41:19<3694::AID-ANIE3694>3.0.CO;2-BLicence: Unspecified

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title = "[(PPH3)Ag(HCB11Me11)]: A complex with intermolecular Ag⋯H3C interactions",

abstract = "Both in the solid state and in solution, the complex, [(PPh3)Ag(HCB11Me11)] displays significant intermolecular Ag ⋯ H3C interactions. This complex serves as a model for the interaction between a d10 metal center and an alkane.",

keywords = "Anions, C-H activation, Carboranes, Phosphane ligands, Silver",

author = "Ingleson, {Michael J.} and Mahon, {Mary F.} and Patmore, {Nathan J.} and Ruggiero, {Giuseppe D.} and Weller, {Andrew S.}",

year = "2002",

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TY - JOUR

T1 - [(PPH3)Ag(HCB11Me11)]

T2 - A complex with intermolecular Ag⋯H3C interactions

AU - Ingleson, Michael J.

AU - Mahon, Mary F.

AU - Patmore, Nathan J.

AU - Ruggiero, Giuseppe D.

AU - Weller, Andrew S.

PY - 2002/10/4

Y1 - 2002/10/4

N2 - Both in the solid state and in solution, the complex, [(PPh3)Ag(HCB11Me11)] displays significant intermolecular Ag ⋯ H3C interactions. This complex serves as a model for the interaction between a d10 metal center and an alkane.

AB - Both in the solid state and in solution, the complex, [(PPh3)Ag(HCB11Me11)] displays significant intermolecular Ag ⋯ H3C interactions. This complex serves as a model for the interaction between a d10 metal center and an alkane.

KW - Anions

KW - C-H activation

KW - Carboranes

KW - Phosphane ligands

KW - Silver

UR - http://www.scopus.com/inward/record.url?scp=0037020418&partnerID=8YFLogxK

U2 - 10.1002/1521-3773(20021004)41:19<3694::AID-ANIE3694>3.0.CO;2-B

DO - 10.1002/1521-3773(20021004)41:19<3694::AID-ANIE3694>3.0.CO;2-B

M3 - Article

C2 - 12370934

AN - SCOPUS:0037020418

VL - 41

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EP - 3697

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 19

ER -

[(PPH₃)Ag(HCB₁₁Me₁₁)]: A complex with intermolecular Ag⋯H₃C interactions

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