Abstract
The reaction of alkyl sulfinates with alkynyl(aryl)iodonium salts provides a facile access into otherwise difficult to obtain alkyl alkynyl sulfones and cyclic vinyl sulfones via 1,2-rearrangement or 1,5-CH insertion, respectively. In benzyl sulfinates, 1,5-CH insertion is not possible, so addition to the aromatic ring occurs, followed by ring expansion to generate novel bicyclic sulfones.
Original language | English |
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Pages (from-to) | 2543-2548 |
Number of pages | 6 |
Journal | Journal of Organic Chemistry |
Volume | 81 |
Issue number | 6 |
DOIs | |
Publication status | Published - 29 Feb 2016 |
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Dive into the research topics of 'Preparation of Alkyl Alkynyl Sulfones and Cyclic Vinyl Sulfones from Alkynyl(aryl)iodonium Salts'. Together they form a unique fingerprint.Profiles
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Wesley Moran
- Department of Chemical Sciences - Reader
- School of Applied Sciences
- Chemical Synthesis and Design Centre - Member
- Structural, Molecular and Dynamic Modelling Centre - Associate Member
Person: Academic