Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes

Raquel Gracia; Harry Adams; Nathan J. Patmore

doi:10.1039/b820287g

Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes

Raquel Gracia, Harry Adams, Nathan J. Patmore

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The Ru–Ru bond length for Ru₂^II,III and Ru₂^II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru–Ru bond order, due to increased internal rotation.

Original language	English
Pages (from-to)	259-261
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	2
Early online date	26 Nov 2008
DOIs	https://doi.org/10.1039/b820287g
Publication status	Published - 14 Jan 2009
Externally published	Yes

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title = "Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes",

abstract = "The Ru–Ru bond length for Ru2II,III and Ru2II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru–Ru bond order, due to increased internal rotation.",

author = "Raquel Gracia and Harry Adams and Patmore, {Nathan J.}",

year = "2009",

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doi = "10.1039/b820287g",

language = "English",

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publisher = "Royal Society of Chemistry",

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AU - Gracia, Raquel

AU - Adams, Harry

AU - Patmore, Nathan J.

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Y1 - 2009/1/14

N2 - The Ru–Ru bond length for Ru2II,III and Ru2II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru–Ru bond order, due to increased internal rotation.

AB - The Ru–Ru bond length for Ru2II,III and Ru2II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru–Ru bond order, due to increased internal rotation.

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U2 - 10.1039/b820287g

DO - 10.1039/b820287g

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JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 2

ER -

Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes

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